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MHT CET · Chemistry · Coordination Compounds

What is the coordination number of central metal ion in \(\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}\) ?

  1. A 2
  2. B 4
  3. C 6
  4. D 12
Verified Solution

Answer & Solution

Correct Answer

(C) 6

Step-by-step Solution

Detailed explanation

Oxalate ligand (bidentate) \(\mathrm{C}_2 \mathrm{O}_4{ }^{2-}\) utilizes electron pair on each of its negatively charged oxygen atoms for linking with central metal. Hence, at a time, it coordinates with the metal ion through 2 oxygen atoms.

Therefore, on binding with 3 oxalate ions, the coordination number of \(\mathrm{Fe}^{3+}\) will be 6 .