MHT CET · Chemistry · Chemical Kinetics

What is rate constant of a first order reaction if time required to decrease concentration of reactant from \(1.6 \mathrm{M}\) to \(0.4 \mathrm{M}\) is 12 hours?

A 0.116 hour \(^{-1}\)
B 0.167 hour \(^{-1}\)
C 0.4 hour \(^{-1}\)
D 0.78 hour \(^{-1}\)

Verified Solution

Answer & Solution

Correct Answer

(A) 0.116 hour \(^{-1}\)

Step-by-step Solution

Detailed explanation

We know
\(\begin{aligned} \mathrm{K} & =\frac{2.303}{\mathrm{t}} \log \frac{\mathrm{a}_0}{\mathrm{a}_{\mathrm{t}}} \\ & =\frac{2.303}{12} \log \frac{1.6}{0.4} \\ & =\frac{2.303}{12} \log ^4 \\ & =\frac{2.303}{12} \times 2 \log ^2 \\ & =0.115\end{aligned}\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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