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MHT CET · Chemistry · Electrochemistry

What is molar conductivity at zero concentration in \(\Omega^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}\) for aluminium sulphate, if molar ionic conductivities at zero concentration of \(\mathrm{Al}^{+3}\) and \(\mathrm{SO}_4^{-2}\) are \(189 \Omega^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}\) and \(50 \cdot 1 \Omega^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}\) respectively?

  1. A \(239 \cdot 1\)
  2. B \(428 \cdot 1\)
  3. C \(478 \cdot 2\)
  4. D \(528 \cdot 3\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(528 \cdot 3\)

Step-by-step Solution

Detailed explanation

\(\Lambda_m^0 = \nu_{\mathrm{Al}^{+3}} \lambda^0_{\mathrm{Al}^{+3}} + \nu_{\mathrm{SO}_4^{-2}} \lambda^0_{\mathrm{SO}_4^{-2}}\) \(\Lambda_m^0 = (2 \times 189) + (3 \times 50.1)\)