MHT CET · Chemistry · Chemical Kinetics
The reaction given below \(2 \mathrm{NH}_{3(\mathrm{~g})} \xrightarrow{\mathrm{Pt}} \mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(\mathrm{~g})}\) has rate of reaction \(2.5 \times 10^{-6} \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\) formation of \(\mathrm{H}_{2(\mathrm{~g})}\) ?
- A \(2.5 \times 10^{-6} \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\)
- B \(3.75 \times 10^{-6} \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\)
- C \(5.0 \times 10^{-6} \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\)
- D \(7.5 \times 10^{-6} \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\)
Answer & Solution
Correct Answer
(D) \(7.5 \times 10^{-6} \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\)
Step-by-step Solution
Detailed explanation
\(\text {For the reaction, } 2 \mathrm{NH}_{3(\mathrm{~g})} \xrightarrow{\mathrm{Pt}} \mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(\mathrm{~g})} \)
\( \text {Rate of reaction }=-\frac{1}{2} \frac{\mathrm{~d}\left[\mathrm{NH}_3\right]}{\mathrm{dt}}=\frac{\mathrm{d}\left[\mathrm{N}_2\right]}{\mathrm{dt}}\)\(=\frac{1 \mathrm{~d}\left[\mathrm{H}_2\right]}{3} \)
\( \therefore 2.5 \times 10^{-6}=\frac{1}{3} \frac{\mathrm{~d}\left[\mathrm{H}_2\right]}{\mathrm{dt}} \)
\( \therefore \frac{\mathrm{d}\left[\mathrm{H}_2\right]}{\mathrm{dt}}=3 \times 2.5 \times 10^{-6}=7.5 \times 10^{-6}\)\(\mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\)
\( \text {Rate of reaction }=-\frac{1}{2} \frac{\mathrm{~d}\left[\mathrm{NH}_3\right]}{\mathrm{dt}}=\frac{\mathrm{d}\left[\mathrm{N}_2\right]}{\mathrm{dt}}\)\(=\frac{1 \mathrm{~d}\left[\mathrm{H}_2\right]}{3} \)
\( \therefore 2.5 \times 10^{-6}=\frac{1}{3} \frac{\mathrm{~d}\left[\mathrm{H}_2\right]}{\mathrm{dt}} \)
\( \therefore \frac{\mathrm{d}\left[\mathrm{H}_2\right]}{\mathrm{dt}}=3 \times 2.5 \times 10^{-6}=7.5 \times 10^{-6}\)\(\mathrm{~mol} \mathrm{dm}^{-3} \mathrm{sec}^{-1}\)
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- Which from following elements is isoelectronic with \(\mathrm{Na}^{+}\)?MHT CET 2023 Easy
- What is the relation between the vapour pressure of solution, vapour pressure of solvent and its mole fraction in the solution?MHT CET 2024 Medium
- Identify glycosidic linkage present in lactose.MHT CET 2023 Easy
- A solution of nonvolatile solute is obtained by dissolving \(15 \mathrm{~g}\) in \(200 \mathrm{~mL}\) water has depression in freezing point \(0.75 \mathrm{~K}\). Calculate the molar mass of solute if cryoscopic constant of water is \(1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\).MHT CET 2023 Medium
- Electrolytic cells containing \(\mathrm{Zn}\) and \(\mathrm{Al}\) salt solutions are connected in series. If \(6.5 \mathrm{~g}\) of \(\mathrm{Zn}\) is deposited in one cell calculate mass of Al deposited in second cell (molar mass : \(\mathrm{Zn}=65\), \(\mathrm{Al}=27\) ) by passing definite quantity of electricity?MHT CET 2023 Medium
- Which lanthanoid from following may exhibit +4 oxidation state with \(\mathrm{f}^{0}\) configuration?MHT CET 2025 Easy
More PYQs from MHT CET
- An electron moves in Bohr's orbit. The magnetic field at the centre is proportional toMHT CET 2011 Medium
- Photons of wavelength \(\lambda\) ' are incident on the cathode of a photocell. Electrons are emitted from the cathode surface. The de-Broglie wavelength of the emitted electrons is (work function is negligible)
\((\mathrm{c}=\) velocity of light, \(\quad \mathrm{h}=\) Planck's constant, \(\quad \mathrm{m}=\) mass of electron \()\)MHT CET 2020 Medium - Heat energy is incident on the surface of a material at the rate of . If the coefficient of absorption is and the coefficient of reflection is , then the amount of heat energy transmitted through the material in isMHT CET 2018 Medium
- What is IUPAC name of the following compound?
MHT CET 2025 Medium - Identify the reagent used in the following reaction.
Benzoic acid \(\stackrel{\text { Reagent }}{\Delta}\) Benzoyl chloride + Phosphorous oxychloride + Hydrogen chlorideMHT CET 2023 Easy - A solid sphere rolls without slipping on an inclined plane at an angle \(\theta\). The ratio of total kinetic energy to its rotational kinetic energy isMHT CET 2023 Medium