MHT CET · Chemistry · Chemical Kinetics

The rate law for the reaction \(\mathrm{A}+\mathrm{B} \rightarrow\) product is rate \(=k[A][B]\). When will the rate of reaction increase by factor two?

A \([\mathrm{A}]\) and \([\mathrm{B}]\) both are doubled
B \([A]\) is doubled and \([B]\) is kept constant
C \([\mathrm{B}]\) is doubled and \([\mathrm{A}]\) is halved
D \([\mathrm{A}]\) is kept constant \([\mathrm{B}]\) is halved

Verified Solution

Answer & Solution

Correct Answer

(B) \([A]\) is doubled and \([B]\) is kept constant

Step-by-step Solution

Detailed explanation

\(\begin{aligned} & \text { Rate }=\mathrm{k}[\mathrm{A}][\mathrm{B}] \\ & (\text { Rate })_1=\mathrm{k} \times 2[\mathrm{~A}][\mathrm{B}] \\ & \frac{(\text { Rate })_1}{\text { Rate }}=\frac{\mathrm{k} 2[\mathrm{~A}][\mathrm{B}]}{\mathrm{k}[\mathrm{A}][\mathrm{B}]}=2 \\ & (\text { Rate })_1=2 \times \text { Rate }\end{aligned}\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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