MHT CET · Chemistry · Haloalkanes and Haloarenes
The correct order of reactivity for reactions involving cleavage of \(\mathrm{C}-\mathrm{X}\) bond in following compounds is

- A I>III>II
- B III>II>I
- C I>II>III
- D II>III>I
Answer & Solution
Correct Answer
(B) III>II>I
Step-by-step Solution
Detailed explanation
Cleavage of \(\mathrm{C}-\mathrm{X}\) bond occurred by \(\mathrm{Ar}-\mathrm{SN}\) reaction.
Rate of \(\mathrm{Ar}-\mathrm{SN} \propto-\mathrm{M},-\mathrm{I} \propto \frac{1}{+\mathrm{M}+\mathrm{I}}\)
Rate of \(\mathrm{Ar}-\mathrm{SN} \propto-\mathrm{M},-\mathrm{I} \propto \frac{1}{+\mathrm{M}+\mathrm{I}}\)
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