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MHT CET · Chemistry · Electrochemistry

If \(\mathrm{E}^{\circ}\left(\mathrm{Cu}_{(\mathrm{aq})}^{+2} \mid \mathrm{Cu}_{(\mathrm{s})}\right)=+0 \cdot 34 \mathrm{~V}\).
What is potential for \(\mathrm{Cu}_{(\mathrm{s})} \rightarrow \mathrm{Cu}_{(\mathrm{aq})}^{+2}(0 \cdot 1 \mathrm{M})+2 \overline{\mathrm{e}}\) at 298 K ?

  1. A +0.3696 V
  2. B -0.3696 V
  3. C +0.3104 V
  4. D -0.3104 V
Verified Solution

Answer & Solution

Correct Answer

(D) -0.3104 V

Step-by-step Solution

Detailed explanation

\( \mathrm{E}^{\circ} = -0.34 \mathrm{~V} \) \( \mathrm{E} = \mathrm{E}^{\circ} - \frac{0.0592}{n} \log [\mathrm{Cu}^{+2}] \)