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MHT CET · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Identify the reactivity order for halogens towards alkanes.

  1. A \(\mathrm{I}_2\gt\mathrm{Br}_2\gt\mathrm{Cl}_2\gt\mathrm{F}_2\)
  2. B \(\mathrm{Br}_2\gt\mathrm{Cl}_2\gt\mathrm{F}_2\gt\mathrm{I}_2\)
  3. C \(\mathrm{F}_2\gt\mathrm{Cl}_2\gt\mathrm{Br}_2\gt\mathrm{I}_2\)
  4. D \(\mathrm{Cl}_2\gt\mathrm{F}_2\gt\mathrm{Br}_2\gt\mathrm{I}_2\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(\mathrm{F}_2\gt\mathrm{Cl}_2\gt\mathrm{Br}_2\gt\mathrm{I}_2\)

Step-by-step Solution

Detailed explanation

Due to electronegativity difference, the reactivity order for halogens towards alkanes is:
\(\longleftarrow \frac{\mathrm{F}_2\gt\mathrm{Cl}_2\gt\mathrm{Br}_2\gt\mathrm{I}_2}{+\mathrm{I} \text { effect }}\)
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