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MHT CET · Chemistry · Ionic Equilibrium

Find the concentration of sodium acetate when added to 0.1 M solution of acetic acid to form a buffer solution of \(\mathrm{pH}=5.5\) ?
\(\left(\mathrm{pK}_{\mathrm{a}} \text { of } \mathrm{CH}_3 \mathrm{COOH}=4 \cdot 5\right)\)

  1. A 0.1 M
  2. B 0.01 M
  3. C 1.0 M
  4. D 10.0 M
Verified Solution

Answer & Solution

Correct Answer

(C) 1.0 M

Step-by-step Solution

Detailed explanation

\(\mathrm{pH} = \mathrm{pK}_{\mathrm{a}} + \log \left( \frac{[\text{Salt}]}{[\text{Acid}]} \right)\) \(5.5 = 4.5 + \log \left( \frac{[\mathrm{CH}_3\mathrm{COONa}]}{0.1\, \mathrm{M}} \right)\)