MHT CET · Chemistry · Solutions
A solution of nonvolatile solute is obtained by dissolving \(15 \mathrm{~g}\) in \(200 \mathrm{~mL}\) water has depression in freezing point \(0.75 \mathrm{~K}\). Calculate the molar mass of solute if cryoscopic constant of water is \(1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\).
- A \(160 \mathrm{~g} \mathrm{~mol}^{-1}\)
- B \(172 \mathrm{~g} \mathrm{~mol}^{-1}\)
- C \(186 \mathrm{~g} \mathrm{~mol}^{-1}\)
- D \(198 \mathrm{~g} \mathrm{~mol}^{-1}\)
Answer & Solution
Correct Answer
(C) \(186 \mathrm{~g} \mathrm{~mol}^{-1}\)
Step-by-step Solution
Detailed explanation
\(\begin{aligned} \mathrm{M}_2 & =\frac{1000 \mathrm{~K}_{\mathrm{f}} \mathrm{W}_2}{\Delta \mathrm{T}_{\mathrm{f}} \mathrm{W}_1} \\ & =\frac{1000 \times 1.86 \times 15}{0.75 \times 200} \\ & =186 \mathrm{~g} \mathrm{~mol}^{-1}\end{aligned}\)
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