KCET · Chemistry · Solutions
Match List-I (Laws) with the List-II (Mathematical expressions):
| List-I | List-II | ||
|---|---|---|---|
| (a) | Henry's law | (i) | \(p_1 = p_1^0 x_1\) |
| (b) | Raoult's law | (ii) | \(p = K_H \chi\) |
| (c) | First law of thermodynamics | (iii) | \(\Lambda_m = v_+ \lambda_+ + v_- \lambda_-\) |
| (d) | Kohlrausch's law | (iv) | \(\Delta U = q + w\) |
- A a-i, b-ii, c-iii, d–iv
- B a-ii, b-i, c-iii, d–iv
- C a-ii, b-i, c-iv, d–iii
- D a-i, b-ii, c-iv, d–iii
Answer & Solution
Correct Answer
(C) a-ii, b-i, c-iv, d–iii
Step-by-step Solution
Detailed explanation
Henry's law relates the partial pressure of a gas to its mole fraction in solution: \(p = K_H \chi\). Thus, (a) matches (ii).
Raoult's law states that the partial vapour pressure of a component in a solution is proportional to its mole fraction: \(p_1 = p_1^0 x_1\). Thus, (b) matches (i).
The first law of thermodynamics is the law of conservation of energy, expressed as \(\Delta U = q + w\). Thus, (c) matches (iv).
Kohlrausch's law of independent migration of ions gives the limiting molar conductivity of an electrolyte as the sum of the limiting ionic conductivities: \(\Lambda_m = v_+ \lambda_+ + v_- \lambda_-\). Thus, (d) matches (iii).
The correct matching is a-ii, b-i, c-iv, d-iii.
Answer: a-ii, b-i, c-iv, d–iii
Raoult's law states that the partial vapour pressure of a component in a solution is proportional to its mole fraction: \(p_1 = p_1^0 x_1\). Thus, (b) matches (i).
The first law of thermodynamics is the law of conservation of energy, expressed as \(\Delta U = q + w\). Thus, (c) matches (iv).
Kohlrausch's law of independent migration of ions gives the limiting molar conductivity of an electrolyte as the sum of the limiting ionic conductivities: \(\Lambda_m = v_+ \lambda_+ + v_- \lambda_-\). Thus, (d) matches (iii).
The correct matching is a-ii, b-i, c-iv, d-iii.
Answer: a-ii, b-i, c-iv, d–iii
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