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KCET · Chemistry · Solutions

Match List-I (Laws) with the List-II (Mathematical expressions):
List-IList-II
(a)Henry's law(i)\(p_1 = p_1^0 x_1\)
(b)Raoult's law(ii)\(p = K_H \chi\)
(c)First law of thermodynamics(iii)\(\Lambda_m = v_+ \lambda_+ + v_- \lambda_-\)
(d)Kohlrausch's law(iv)\(\Delta U = q + w\)
Codes:

  1. A a-i, b-ii, c-iii, d–iv
  2. B a-ii, b-i, c-iii, d–iv
  3. C a-ii, b-i, c-iv, d–iii
  4. D a-i, b-ii, c-iv, d–iii
Verified Solution

Answer & Solution

Correct Answer

(C) a-ii, b-i, c-iv, d–iii

Step-by-step Solution

Detailed explanation

Henry's law relates the partial pressure of a gas to its mole fraction in solution: \(p = K_H \chi\). Thus, (a) matches (ii).

Raoult's law states that the partial vapour pressure of a component in a solution is proportional to its mole fraction: \(p_1 = p_1^0 x_1\). Thus, (b) matches (i).

The first law of thermodynamics is the law of conservation of energy, expressed as \(\Delta U = q + w\). Thus, (c) matches (iv).

Kohlrausch's law of independent migration of ions gives the limiting molar conductivity of an electrolyte as the sum of the limiting ionic conductivities: \(\Lambda_m = v_+ \lambda_+ + v_- \lambda_-\). Thus, (d) matches (iii).

The correct matching is a-ii, b-i, c-iv, d-iii.

Answer: a-ii, b-i, c-iv, d–iii