Which of the following statement/s is/are wrong?
A. Methylamine is more basic than ammonia.
B. Amines form hydrogen bonds.
C. Ethylamine has higher boiling point than propane.
D. Dimethylamine is less basic than methylamine.
E. Amines are soluble in organic solvents like alcohol.
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The dehydration of alcohol follows the order :

Answer the question on basis of passage given below
The noble gases have closed shell electronic configuration and are monatomic gases under normal conditions. The low boiling points of lighter noble gases are due to the weak dispersion forces between the atoms and the absence of other inter atomic interaction. The direct reaction of xenon with fluorine leads to a series of compounds with oxidation numbers \(+2, +4\) and \(+6\).
\(\text{XeF}_4\) reacts violently with water to give \(\text{XeO}_3\). The compound of Xenon exhibit stereoisomerism and their geometries can be deduced considering the total number of electrons in the valence shell.
Match List - I with List – II.

List - I	List - II
A. Its partial hydrolysis does not change the oxidation state of the central atom	I. He
B. It is used in modern diving apparatus	II. \(\text{XeF}_6\)
C. It is used to provide inert atmosphere for filling electrical bulbs	III. \(\text{XeF}_4\)
D. Its central atom is in \(\text{sp}^3\text{d}^2\) hybridisation state	IV. Ar

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Read the passage given below and answer the question.
The transition elements which give the greatest number of oxidation states occur in or near the middle of the series. Manganese, for example, exhibits all the oxidation states from +2 to +7. The lesser number of oxidation states at extreme ends stems from either too few electrons to lose or share (Sc, Ti) on too many d-electrons (hence fewer orbitals available in which to share electrons with others) for higher valence (Cu, Zn). Thus early in the series scandium (II) is virtually unknown and titanium (IV) is more stable than Ti (III) or Ti (II). At the other end, the only oxidation state of zinc is +2 (no d electrons are involved). The maximum oxidation states of reasonable stability correspond in value to the sum of the s- and d-electrons upto manganese (\(TiO_2, VVO^+, CrVIO_4^{2-}, MnVIIO_4\)) followed by a rather abrupt decrease in stability of higher oxidation states, so that the typical species to follow are \(Fe^{II,III}, Co^{II,III}, Ni^{II}, Cu^{I,II}, Zn^{II}\).
The variability of oxidation states, a characteristic of transition elements, arises out of incomplete filling of d-orbitals in such a way that their oxidation states differ from each other by unity, e.g. \(V^{II}, V^{III}, V^{IV}, V^{V}\). This is in contrast with the variability of oxidation states of non transition elements where oxidation states normally differ by a unit of two.
An interesting feature in the variability of oxidation states of the d-block elements is noticed among the groups (groups 4 through 10). Although in the p-block, the lower oxidation states are favoured by the heavier members (due to inert pair effect), the opposite is true in the groups of d-block. For example, in group 6, Mo(VI) and W(VI) are found to be more stable than Cr(VI). The Cr(VI) in the form of dichromate in acidic medium is a strong oxidising agent, whereas \(MoO_3\) and \(WO_3\) are not.
Low oxidation states are found when a complex compound has ligands capable of \(\pi\)-acceptor character in addition to the \(\sigma\)-bonding. For example, in \(Ni(CO)_4\) and \(Fe(CO)_5\), the oxidation state of nickel and iron is zero.
The elements giving minimum number of oxidation states are in extreme left and right in 3d series.
This is because :

Calculate the magnetic moment of \(K _4\left[ Mn ( CN )_6\right]\) complex:

Answer the question on the basis of passage given below :
Formaldehyde is the first member of the aldehydic series. It is present in green leaves of plants where its presence is supposed to be due to the reaction of \(CO_2\) with water in the presence of sunlight and chlorophyll. Commercially, formaldehyde is obtained by the controlled oxidation of methane in the presence of molybdenum oxide (\(MoO\)) acting as a catalyst. Formaldehyde is a constituent of a number of polymers also called resins. These are non volatile solids or semi solids which are obtained directly from certain plants and can be synthesized in the laboratory.
Match List I with List II

LIST I	LIST II
A. Bakelite formaldehyde resin	I. Condensation polymers
B. Melamine formaldehyde resin	II. Phenol and formaldehyde
C. Urea formaldehyde resin	III. Melamine and formaldehyde
D. Bakelite \(\&\) Melamine formaldehyde resin	IV. Unbreakable cups and laminated sheets

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Molecules in solids are held together by dipole - dipole interactions. Identify the polar molecules from the following.
A. Solid \(SO_2\)
B. \(NH_3\)
C. \(Cl_2\)
D. \(HCl\)
E. \(He\)
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Arrange the following alcohols in increasing order of their boiling points.
(A) Propan-1-ol
(B) Butan-2-ol
(C) Butan-1-ol
(D) Pentan-1-ol
Choose the correct answer from the options given below:

Match List-l with List-ll

List-l (Rate expression)	List-II (Overall order of reaction)
(A) \(r=k[A]^{0.2}[B]^{0.3}[C]\)	(I) \(\frac{3}{10}\)
(B) \(r=k[A]^{0.2}[B]^{-0.3}[C]\)	(II) 1
(C) \(r=k[A][B]^{0.8}[C]^{-1}\)	(III) \(3 / 2\)
(D)\(r=k[A]^{0.2}[B]^{0.3}[C]^{0.5}\)	(IV) \(9 / 10\)

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Answer the question on basis of passage given below :
P block elements are placed in groups 13 to 18 of the periodic table. Their valence shell electronic configuration is \(ns^2 np^{1-6}\). Group 16 of the p block elements are known as the group of chalcogens having \(ns^2 np^4\) as their general electronic configuration. They exhibit number of oxidation states but the stability of \(- 2\) oxidation state decreases down the group. They are sometimes also known as group of chalcogens as the name is derived from the Greek word for brass and points to the association of sulphur and its congeners with copper. Their ionisation enthalpy decreases down the group. Oxygen shows anomalous behaviour due to its small size and high electronegativity.
Identify the epsom salt out of the following salts :

Arrange the steps of gel electrophoresis in a proper sequence :
(A) Fragments of DNA are separated under an electric field in agarose gel
(B) DNA bands are cut out from the agarose gel and extracted
(C) DNA fragments are visualized by exposure to UV radiation
(D) Separated DNA fragment stained with ethidium bromide
Choose the correct answer from the options given below

The power of some lenses are given below:
A. 2 D \(\quad\) B. 2 \(\quad\) C. 50\(\quad\) D. 100 D
Which lenses are most suitable to construct a compound Microscope with objective lens and Eyepiece, respectively?
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9 cells each of emf e = 3 V and internal resistance r = 1 \( \Omega \) are connected in m = 3 rows, each having n = 3 cells in series. The current flowing in the external resistance of R = 5 \( \Omega \) connected across this arrangement of the cells is