Which of the following sols are correctly matched with their corresponding charges ?
(A) \(\text{Cr(OH)}_3\) sol : negatively charged sol
(B) \(\text{TiO}_2\) sol : positively charged sol
(C) \(\text{CdS}\) sol: positively charged sol
(D) Gum: negatively charged sol
(E) Silver sol : positively charged sol
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The total EMF of a voltaic cell is greater than zero. Which of the following statements is true?

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Replacement of a hydrogen atom in a hydrocarbon by an alkoxy or carboxyl group yields a class of compounds known as ethers. Ethers are classified as symmetrical or unsymmetrical on the basis of groups attached to the oxygen atoms. Diethyl ether, a symmetrical ether, has been widely used as an inhalation anesthetic. Ethers can be prepared by acid catalyzed intermolecular dehydration of alcohols and Williamson's synthesis. Acid catalyzed dehydration of alcohols is not generally preferred as it gives a mixture of elimination and substitution products. In Williamson's synthesis, an alkyl halide is allowed to react with sodium alkoxide. Ethers containing substituted Alkyl groups may also be prepared by this method. The C-O bond in ether is weakly polar and is cleaved under drastic conditions with excess of hydrogen halides. In electrophilic substitution, the alkoxy group deactivates the aromatic ring and directs the incoming group to ortho and para positions.
When ethanol is dehydrated in the presence of H₂SO₄, at 443 K and 413 K respectively, the products formed are

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Carbohydrates are essential for both plants and animals. Some common examples of carbohydrates are glucose, fructose, sucrose, glycogen, cellulose and starch. They form a major portion of our food. Honey has been used for a long time as an instant source of energy in Ayurvedic medicine. Carbohydrates are used as storage molecules in both plants and animals. The cell wall of bacteria and plants is made of cellulose. We use cellulose in the form of wood for making furniture and as cotton fiber for clothing. They also provide raw material for textiles, paper, lacquers, and breweries. Carbohydrates are classified as Monosaccharides, Oligosaccharides and Polysaccharides on the basis of their behavior towards hydrolysis. Monosaccharides cannot be hydrolyzed further to simpler units whereas oligosaccharides can yield 2-10 units of monosaccharides on hydrolysis. Polysaccharides, which are non-sugars yield a large number of monosaccharide units on hydrolysis.
Answer the following questions about carbohydrates:
The sugar having ẞ-glycosidic linkage is

Choose the correct statement/statements:
(A) Denaturation of protein causes loss of secondary and tertiary structure
(B) Nucleotides are joined together by diester linkage
(C) DNA contains Adenine, Guanine, cytosine and Uracil
(D) Amino acids show amphoteric behaviour
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Aldehydes, carboxylic acids and ketones are widespread in the animal and plant kingdoms. They play a pivotal role in various biochemical processes of life. Their presence in nature adds fragrance and flavor. These compounds are widely used in food products, pharmaceuticals, paints, resins and other important product industries. These compounds are prepared by various laboratory methods, which mainly include oxidation, formylation, acylation and reduction. Due to the polar nature of the carbonyl group in aldehydes and ketones, they can exhibit different reactions like nucleophilic addition. They do exhibit redox and various condensation reactions which lead to the formation of various important compounds. On the other hand, the carboxylic acids are mainly prepared by oxidation and hydrolysis of different compounds. The carboxylic acid consists of a carbonyl group and the hydroxy group (attached to the carbonyl carbon atom). This makes it possible for the carboxylic acid to participate in various chemical reactions which involve cleavage of the C-OH bond and the O-H bond along with the reactions involving the complete - COOH group.
The reagent which doesn't react with both acetone and benzaldehyde is :

The spin-only magnetic moment of \(\left[ MBr _4\right]^{2-}\) is 5.9 BM.
The metal M is:

In a potentiometre, the balanced point is obtained when :

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Plasmodium, a tiny protozoan is responsible for the disease malaria. Different species of Plasmodium (P. vivax, P. malaria and P. falciparum) are responsible for different types of malaria. Of these, malignant malaria caused by Plasmodium falciparum is the most serious one and can even be fatal. Innate immunity consist of four types of barriers. These are – (i) Physical barriers- skin on our body is the main barrier which prevents entry of the micro-organisms. (ii) Physiological barriers- Acid in the stomach, saliva in the mouth, tears from eyes-all prevent microbial growth. (iii) Cellular barriers- Certain types of leukocytes (WBC) of our body like polymorpho-nuclear leukocytes (PMNL-neutrophils) and monocytes and natural killer (type of lymphocytes) in the blood as well as macrophages in tissues can phagocytose and destroy microbes. (iv) Cytokine barriers- virus-infected cells secrete proteins called interferons which protect non-infected cells from further viral infection. Allergy is due to the release of chemicals like histamine and serotonin from the mast cells. The use of drugs like anti-histamine, adrenalin and steroids quickly reduce the symptoms of allergy. Drugs like barbiturates, amphetamines, benzodiazepines, and other similar drugs, that are normally used as medicines to help patients cope with mental illnesses like depression and insomnia, are often abused.
Which one of the followings is not the example of cellular barrier?

According to Bohr's theory, the angular momentum of an electron revolving in the second orbit of the hydrogen atom will be:

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When a metal is placed in a solution of its ions, the metal can lose electron and can go in the solution as ion or the metal ion in the solution can take electron from the electrode and get deposited as metal. Thus, the electrode acquires either positive or negative charge with respect to the solution leading to the development of a potential difference between the metal electrode and the solution. This potential difference is called the electrode potential of the metal. The electrode potential of a metal is a measure of relative tendency to undergo oxidation (loss of electron) or reduction (gain of electron). When the concentration of the ions in the solution is unity, the electrode potential is called standard electrode potential. The magni of potential depends upon the nature of electrode, concentration of ions in solution and the temperature. In a galvanic cell, the electrode at which oxidation occurs is known as anodic half-cell and the electrode at which reduction occurs is known as cathodic half cell. The emf of the cell in terms of standard reduction potential is given by \(E_{\text {cell }}^{\circ}=E_{\text {cathode }}^{\circ}-E_{\text {anode. }}^{\circ}\).The standard free energy change of the redox reaction taking place in the cell is related to \(E_{\text {cell }}^{\circ}\) by \(\Delta G^{\circ}=-n F E^{\circ}\). A redox reaction would occur spontaneously if the free energy change is negative. The equilibrium constant of the reaction is related to the standard free energy change by \(\Delta G^{\circ}=-R T \ln K\).
The equillibrium constant of a feasible cell reaction is

A card is picked up at random from 52 playing cards. Given that the picked card is a queen, then the probability of this card to be a card of spade is:

Identify the terminal methods to prevent pregnancy.
(A) Tubectomy
(B) Vasectomy
(C) IUDs
(D) Cervical caps
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