Which of the following amines can be prepared by Gabriel synthesis ?
(A) Isobutyl amine
(B) 2-Phenyl ethylamine
(C) N-Methyl benzyl amine
(D) Aniline
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Unit of rate constant for sero order reaction is:

Fructose is a ketohexose. The keto group is positioned at which carbon:

For a particular reaction taking place at \(\text{T} = 300 \text{ K}\), \(\text{E}_a= 300 \text{ kJ/mol}\) and \(\text{log k} = -3.45\); calculate the temperature at which the rate constant becomes 4 times that of k. (Given \(\text{log } 2 = 0.3010\))

Consider the following reaction:
\(Ph-CH(Cl)-CH_3 \xrightarrow[\Delta]{\text{ alc. } KCN}\text {?}\)
The product formed is:

Isopropylbromide reacts with silver nitrite to form major product as

Match List-l with List-II

List-l (Solutions)	List-II (Explanation)
(A) Saturated solution	(I) Solution having two components.
(B) Isotonic solutions	(II) A solution whose osmotic pressure is more than that of another.
(C) Binary solution	(III) A solution which contains the maximum amount of solute that can be dissolved in a given amount of solvent at a given temperature.
(D) Hypertonic solution	(IV) The solutions having same osmotic pressure at a given temperature.

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If the order of matrix \(A\) is \(4 \times 3\), order of matrix \(B\) is \(4 \times 5\) and order of matrix \(C\) is \(5 \times 3\), then the order of matrix \((B \cdot C) A^{\prime}\) is :

Match List - I with List - II

List - I	List - II
(A) Impurity defect	(I) NaCl with anionic sites called F centres
(B) Metal excess defect	(II) FeO with Fe3+
(C) Metal deficiency defect	(III) Non ionic solids and density of solid decreases
(D) Simple vacancy defect	(IV) NaCl with Sr2+ and cationic sites vacant

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Read the passage carefully and answer the following questions
Aldehydes, carboxylic acids and ketones are widespread in the animal and plant kingdoms. They play a pivotal role in various biochemical processes of life. Their presence in nature adds fragrance and flavor. These compounds are widely used in food products, pharmaceuticals, paints, resins and other important product industries. These compounds are prepared by various laboratory methods, which mainly include oxidation, formylation, acylation and reduction. Due to the polar nature of the carbonyl group in aldehydes and ketones, they can exhibit different reactions like nucleophilic addition. They do exhibit redox and various condensation reactions which lead to the formation of various important compounds. On the other hand, the carboxylic acids are mainly prepared by oxidation and hydrolysis of different compounds. The carboxylic acid consists of a carbonyl group and the hydroxy group (attached to the carbonyl carbon atom). This makes it possible for the carboxylic acid to participate in various chemical reactions which involve cleavage of the C-OH bond and the O-H bond along with the reactions involving the complete - COOH group.
Identify the incorrect statement for Cannizaro reaction.

The first clinical gene therapy was given in 1990 to a 4-year-old girl with ___________ .

The value of \(\tan ^2\left(\sec ^{-1} 2\right)+\cot ^2\left(\operatorname{cosec}^{-1} 3\right)\) is:

Arrange the following steps of replication of retrovirus in correct sequence
A. Incorporation of viral DNA into host genome.
B. Formation of viral DNA by reverse transcription.
C. Infection of normal cell by virus and introduction of viral RNA into host
D. Production of new viral RNA by infected cells.
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