Which of the following alkyl halide will undergo \(S_N1\) reaction most readily :

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Many halogen containing organic compounds are present in nature and some of them are clinically useful. These classes of organic compounds find a wide range of applications in our daily life as well as in industries. Many of the polyhalogen compounds are useful too in agriculture. However, some of these compounds cannot be easily decomposed and are thus considered to be environmental hazards. These halo compounds are prepared via different synthetic routes where a variety of organic compounds can be used as substrates such as amines, hydrocarbons etc. They are used as solvents for relatively non-polar compounds. These compounds exhibit substitution and elimination reactions, in addition to their reactions with different metals, which leads to the formation of a versatile starting material for others organic compounds.
Which halocompound is used for the treatment of malaria?

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Carbonyl compounds such as aldehydes, ketones, and carboxylic acids play an important role in the biochemical process of plants and animal kingdom. Many aldehydes and ketones find applications in dye, perfumery and other industries.
The carbonyl carbon atom is \(s p^2\)-hybridized forming three sigma and one pi-bond with oxygen.
C-O bonds are polar bond due to high electronegativity of oxygen than carbon.
Hence the carbonyl carbon behaves as an electrophilic center and oxygen as a nucleophilic centre.
Primary and secondary alcohols yield aldehydes and ketones respectively upon oxidation with variety of oxidixing agents.
The boiling points of aldehydes and ketones differ from hydrocarbons and ethers.
Aldehydes and ketones undergo nucleophilic addition reaction due to presence of electrophilic carbonyl carbon.
Nucleophile and a proton add across the carbon oxygen double bond.
In polar C-O bond in carbonyl compounds, the nature of carbon and oxygen atom is

In the following examples, select the primary alkyl halide
(A). 1-Bromo-3-methylbutane
(B). 2-Bromo-2-methylbutane
(C). 3-Bromo propene
(D). Chlorophenyl methane
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The molality of a solution prepared by dissolving \(4 . 0 ~ g ~ N a O H\) in \(1 0 0 0 ~ m L\) distilled water is _________ (Assume that the density of water is \(1 g mL ^{-1}\) )

Sucrose on hydrolysis gives:

\(\Delta G = \Delta H – T\Delta S\)
When \(\Delta H = -ve\) and \(\Delta S = -ve\), then the value of \(\Delta G\) will :

According to species-area relationships, the relation between species richness and area for a wide variety of taxa (angiosperms, birds, bats and freshwater fishes) turns out to be a:

\(0.1\) M aqueous solution of the following salts were prepared. Their conductivity values were measured at \(25\circ C\). Which of the following will possess least conductivity at \(25\circ C\)?

Which of the following are the salient features of Human Genome project?
(A) The average gene consists of 3000 bases, but sizes vary greatly.
(B) Chromosome 1 has most genes (2968), and the Y has the fewest (231).
(C) The total number of genes is estimated at 30,000- much lower than previous estimates of 80,000 to 1,40,000 genes.
(D) Repetitive sequences are stretches of DNA sequences that are repeated many times, sometimes hundred to thousand times.
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If \(A=\left[a_{i j}\right]_{3 \times 3}\), where \(a_{i j}=\frac{(-1)^{i+j}-1, i=j}{(-1)^{i+j}, i \neq j}\) then the value of \(A+A^T\) is:

Which one of the following statements is not correct regarding the DNA?

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Certain types of leukocytes (WBC) of our body like polymorpho-nuclear leukocytes (PMNL-neutrophils) and monocytes and natural killer (type of lymphocytes) in the blood as well as macrophages in tissues can phagocytose and destroy microbes. For determining the cause of allergy, the patient is exposed to or injected with very small doses of possible allergens, and the reactions studied. The use of drugs like anti-histamine, adrenalin and steroids quickly reduce the symptoms of allergy. Heroin, commonly called smack is chemically diacetylmorphine which is a white, odourless, bitter crystalline compound. This is obtained by acetylation of morphine. Techniques like radiography (use of X-rays), CT (computed tomography) and MRI (magnetic resonance imaging) are very useful to detect cancers of the internal organs. Different species of Plasmodium (P. vivax, P. malaria and P. falciparum) are responsible for different types of malaria. Of these, malignant malaria caused by Plasmodium falciparum is the most serious one and can even be fatal.
Which of the following cells are involved in phagocytosis and destruction of microbes?