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CUET · CHEMISTRY · PYQ PAPER 2023

Which of the complexes give white precipitate when treated with aqueous solution of \(BaCl_2\)?
\(\left[ Co \left( NH _3\right)_5 SO _4\right] Cl\)
\(\left[ Co \left( NH _3\right)_5 Cl \right] SO _4\)
\(\left[ Co \left( NH _3\right)_5\left( NO _2\right)\right]\left( NO _2\right)_2\)
\(\left[ Co \left( NH _3\right)_5 CN \right] SO _4\)
Choose the correct answer from the options given below :

  1. A B, C only
  2. B B, D only
  3. C A, C only
  4. D A, C, D only
Verified Solution

Answer & Solution

Correct Answer

(B) B, D only

Step-by-step Solution

Detailed explanation

Complexes with outer sphere sulfate ions react with \(BaCl_2\). B: \(\left[ Co \left( NH _3\right)_5 Cl \right] SO _4\) D: \(\left[ Co \left( NH _3\right)_5 CN \right] SO _4\) B, D only.
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