CUET · CHEMISTRY · PYQ PAPER 2025
What happens when a tertiary alcohol is heated at temperature of 443 K in presence of phosphoric acid?
- A Ether is formed
- B Alkene is formed
- C Mixture of alkene and alcohol is formed
- D No reaction takes place
Answer & Solution
Correct Answer
(B) Alkene is formed
Step-by-step Solution
Detailed explanation
Alkene is formed
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\(KMnO _4\) is prepared by the fusion of \(MnO _2\) with an alkali metal hydroxide and an oxidizing agent like \(KNO _3\) to give a dark-green manganate ion which disproportionate to give permanganate as follows.
\(\begin{array}{l}2 MnO _2+4 KOH + O _2 \rightarrow 2 K_2 MnO _4+2 H _2 O \\ 3 K_2 MnO _4+4 H ^{+} \rightarrow 2 KMnO _4+ MnO _2+2 H _2 O \end{array}\)
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