The vapour pressure of pure water at \(25^{\circ} C\) is 23.75 mmHg.
The vapour pressure of the solution obtained by dissolving 34.2 g of sucrose \(\left( C _{12} H _{22} O _{11}\right)\) in 100 g of water will be :

Which of the following compound(s) does not react with Fehling solution?
(A) \(CH _3 CHO\)
(B) \(Ph - CHO\)
(C) Glucose
(D)

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Which of the following statement(s) is/are correct with reference to electrophilic aromatic substitution of \(\text{C}_6\text{H}_5\text{Cl}\)?
(A) Cl acts as an activating and o/p directing group
(B) Cl acts as a deactivating and o/p directing group
(C) acts as an activating and m directing group
(D) Cl acts as a deactivating and m directing group
(E) Presence of \(\text{NO}_2\) at p-position facilitates the reactions
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Match the complex given in List - I with the number of unpaired electrons given in List - II

List-I (Complex)	List-II (Number of unpaired electrons (n))
(A) \(\left[ NiCl _4\right]^{2-}\)	(I) 5
(B) \(\left[ Co \left( NH _3\right)_6\right]^{3 +}\)	(II) 1
(C) \(\left[ FeF _6\right]^{3-}\)	(III) 2
(D) \(\left[ Fe ( CN )_6\right]^{3-}\)	(IV) \(0\)

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Read the passage carefully and answer the following questions
Aldehydes, carboxylic acids and ketones are widespread in the animal and plant kingdoms. They play a pivotal role in various biochemical processes of life. Their presence in nature adds fragrance and flavor. These compounds are widely used in food products, pharmaceuticals, paints, resins and other important product industries. These compounds are prepared by various laboratory methods, which mainly include oxidation, formylation, acylation and reduction. Due to the polar nature of the carbonyl group in aldehydes and ketones, they can exhibit different reactions like nucleophilic addition. They do exhibit redox and various condensation reactions which lead to the formation of various important compounds. On the other hand, the carboxylic acids are mainly prepared by oxidation and hydrolysis of different compounds. The carboxylic acid consists of a carbonyl group and the hydroxy group (attached to the carbonyl carbon atom). This makes it possible for the carboxylic acid to participate in various chemical reactions which involve cleavage of the C-OH bond and the O-H bond along with the reactions involving the complete - COOH group.
Identify the incorrect statement for Cannizaro reaction.

Name the reagent required to convert cyclohexene into hexane-1, 6-dioic acid.

Hell-Volhard Zelinsky reaction is used for the formation of

The number of all possible matrices of order \(2 \times 3\) with each entry 0 or 1 is:

Match List - I with List - II

List - I	List - II
(A) \([Ni(CN)_4]^{2-}\)	(I) \(EDTA^{4-}\)
(B) bidentate	(II) paramagnetic
(C) chelate ligand	(III) diamagnetic
(D) \([Ni(Cl)_4]^{2-}\)	(IV) oxalate

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A wire is stretched to increase its length by 4 times. The resistance of the wire will :

Arrange the following in decreasing order of the basic character in aqueous phase
(A) Ethanamine
(B) Benzeneamine
(C) Phenylmethanamine
(D) N-methylaniline
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The decomposition of ammonia on platinum surface is a zero order reaction. How much time it will take for \(1 \times 10^{-4}\ mol\ L^{-1}\) of ammonia to reduce into half of its concentration ?
(\(K = 0.5 \times 10^{-4}\ mol\ L^{-1}\ s^{-1}\))

On what basis Scandium is considered as transition metal, but Zinc is not considered as transition metal?