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CUET · CHEMISTRY · PYQ PAPER 2023

The standard reduction potentials of \(Mg^{2+}/Mg, Pb^{2+}/Pb\) and \(Sn^{2+}/Sn\)
are \(-2.36, -0.13\) and \(-0.14\) V respectively.
The reaction \(X + Y^{2+} \rightarrow X^{2+} + Y\) will be spontaneous when :

  1. A X = Mg, Y = Pb
  2. B X = Pb, Y = Sn
  3. C X = Pb, Y = Mg
  4. D X = Sn, Y = Mg
Verified Solution

Answer & Solution

Correct Answer

(A) X = Mg, Y = Pb

Step-by-step Solution

Detailed explanation

\(E^\circ_{cell} = E^\circ_{reduction}(Y^{2+}/Y) - E^\circ_{reduction}(X^{2+}/X)\) For X = Mg, Y = Pb: \(E^\circ_{cell} = E^\circ(Pb^{2+}/Pb) - E^\circ(Mg^{2+}/Mg) = -0.13 - (-2.36) = 2.23 \text{ V}\) Since \(E^\circ_{cell} > 0\), the reaction is spontaneous. X = Mg, Y = Pb
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