CUET · CHEMISTRY · PYQ PAPER 2024
The source of electrical energy on the Apollo moon flight was:
- A Lead storage battery
- B A generator set
- C Ni -Cd cells
- D \(H _2- O _2\) fuel cell
Answer & Solution
Correct Answer
(D) \(H _2- O _2\) fuel cell
Step-by-step Solution
Detailed explanation
\(H _2- O _2\) fuel cell
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Amines are classified as primary \(\left(1^{\circ}\right)\), secondary \(\left(2^{\circ}\right)\) and tertiary \(\left(3^{\circ}\right)\) depending upon the number of hydrogen atoms replaced by alkyl or aryl groups in ammonia molecules. Aliphatic amines are a stronger bases due to \(+I\) effect of an alkyl groups.
Intermolecular hydrogen bonding in primary and secondary amines affects the boiling points of amines. The intermolecular association is more in primary amines than in secondary amines as there are more number of hydrogen atoms available for hydrogen bond formation. Nitro compounds are reduced to amines by passing hydrogen gas in the presence of finely divided nickel, palladium or platinum and also by reduction with metals in an acidic medium. Gabriel synthesis is used for the preparation of primary amines. Primary amines react with nitrous acid to give unstable diazonium-salts which can be used to synthesize a variety of compounds.
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A homogeneous mixture of two or more than two components has uniform composition and properties. The binary solutions have two components, which may be solid, liquid or gas. The resultant solution has a larger amount of solvent and a smaller amount of solute. The amount of solute in a given amount of solvent decides the concentration of the resulting solution. The concentration can be expressed in various ways, like molarity, molality, normality and mole fraction.
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Organic compounds derived from NH3 by replacing one or more H-atoms with alkyl or aryl groups will form primary, secondary and tertiary amines. The common methods which include their preparations are reduction of nitro group, amide group and nitrile group, Gabriel phthalimide synthesis and ammonolysis of alkyl halides. Amines are basic in nature due to the presence of a lone pair of electrons on the nitrogen atom. Important chemical properties of amines include acylation, alkylation and their interaction with nitrous acid. There are various tests which can distinguish different types of amines from each other, for e.g. carbylamine test, Hinsberg's test, coupling reaction etc. Another important class of compounds which can be derived from primary amines is azo compounds. These compounds are intensely colored and widely used as dyes in textile, leather and food industries.
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