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CUET · CHEMISTRY · PYQ PAPER 2023

The pair(s) of co-ordination complexes/ions exhibiting the same kind of isomerism is/are :
(A) \(\left[ Cr \left( NH _3\right)_5 Cl \right] Cl _2\) and \(\left[ Cr \left( NH _3\right)_4 Cl _2\right] Cl\)
(B) \(\left[ Co \left( NH _3\right)_4 Cl _2\right]^{+}\)and \(\left[ Pt \left( NH _3\right)_2\left( H _2 O \right) Cl \right]^{+}\)
(C) \(\left[ CoBr _2 Cl _2\right]^{2-}\) and \(\left[ PtBr _2 Cl _2\right]^{2-}\)
(D) \(\left[ Pt \left( NH _3\right)_3\left( NO _3\right)\right] Cl\) and \(\left[ Pt \left( NH _3\right)_3 Cl \right] Br\)
Choose the correct answer from the options given below :

  1. A (A) and (C) only
  2. B (B) and (D) only
  3. C (A) and (D) only
  4. D (C) and (D) only
Verified Solution

Answer & Solution

Correct Answer

(B) (B) and (D) only

Step-by-step Solution

Detailed explanation

(A) \(\left[ Cr \left( NH _3\right)_5 Cl \right] Cl _2\): Ionization isomerism. (A) \(\left[ Cr \left( NH _3\right)_4 Cl _2\right] Cl\): Ionization, Geometrical isomerism. (A) Not the same kind of isomerism. (B) \(\left[ Co \left( NH _3\right)_4 Cl _2\right]^{+}\): Geometrical…
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