The order of basic strength of amines in aqueous solution is :

The boiling point elevation constant \(K_b\) is also known as:

Match List-I With List-II

LISt – I (Solution)	LIST – II (Properties)
(A) Phenol and aniline	(I) Minimum boiling azeotrope
(B) Nitric acid and water	(II) Maximum boiling azeotrope
(C) Ethanol and water	(III) Hydrogen bonding
(D) Benzene and toluene	(IV) Ideal solution

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Answer the question on the basis of passage given below :
Aldehydes and ketones represent two essential classes of organic compounds which are extensively used in the synthesis of a wide variety of other organic molecules.
Due to the inherent polarity of the central carbonyl group, these substances readily undergo nucleophilic addition reactions.Broadly speaking, these addition reactions can be categorized into two types:
one in which simple addition of the nucleophilic reagent occurs across the \(> C = O\) bond, and the second type where the initial addition is subsequently followed by the elimination of a water molecule.
A variety of ammonia derivatives, including hydroxylamine, hydrazine, phenylhydraaine, 2, 4-dinitroplhenylhdrazine, and semicarbazide, all belong to this second category of reactions.
These specific derivatives are fundamentally used for the identification and definitive characterization of aldehydes and ketones. Significantly, both types of nucleophilic addition reactions are strongly influenced by both steric and electronic factors.
As a general rule, aliphatic aldehydes exhibit higher reactivity compared to aromatic aldehydes.
The aliphatic aldehydes demonstrate the ability to reduce both Fehling's solution and Tollen's reagent, whereas aromatic aldehydes are limited to reducing only Tollen's reagent.
In a similar manner to aldehydes, aromatic ketones are observed to be less reactive than aliphatic ketones towards all nucleophilic addition reactions.
In a separate context, phenols and carboxylic acids both exhibit acidic properties in nature.
Both classes of compounds readily dissolve in NaOH solution and cause blue litmus to turn red.
However, carboxylic acids stand out as much stronger acids than phenols and thus can decompose sodium bicarbonate \(\left( NaHCO _3\right)\) with the distinct evolution of \(CO _2\) gas, a reaction which phenols do not undergo.
It is important to note that both electron- donating and electron- withdrawing substituents significantly influence the acid strength of both aliphatic as well as aromatic carboxylic acids.
Furthermore, unlike all other common aliphatic acids, formic acid uniquely possesses reducing properties and simultaneously does not display the typical reactions characteristic of the alkyl group.
Carboxylic acid do not give the characteristic reaction of carbonyl group because:

We have four aqueous solution labelled as :
(A) 0.1 M NaCl
(B) 0.01 M NaCl
(C) \(0.01 M BaCl _2\)
(D) 0.01 M Sucrose
Choose the correct increasing order of Van't Hoff factor from the options given below :

Read the passage carefully and answer the Questions
Werner in 1898, propounded his theory of coordination compounds. In coordination compounds metals show two types of linkages (valences)-primary and secondary. The primary valences are normally ionisable and are satisfied by negative ions. The secondary valences are non-ionisable. These are satisfied by neutral molecules or negative ions. The secondary valence is equal to the coordination number and is fixed for a metal. The ions or group bound by the secondary linkages to the metal have characteristic spatial arrangements corresponding to the different coordination numbers. Both double salts as well as complexes are formed by the combination of two or more stable compounds in stoichiometric ratio. However, they differ in the fact that double salts such as carnallite, Mohr's salt, potash alum etc. dissociate into simple ions completely when dissolved in water. But complex ions do not dissociate completely into simple ions.
When \(1 mol CrCl _3 \cdot 6 H _2 O\) is treated with excess of \(AgNO _3, 3 mol\) of AgCl are obtained. The formula of the complex is:

Match List - I with List - II.

List - I	List - II
(A) Insulin	(I) Carbohydrate metabolism
(B) Glucocorticoids	(II) Controls blood sugar level
(C) Mineralocorticoids	(III) Low level of thyroxine
(D) Hypothyroidism	(IV) Control levels of excretion of salt

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The Medical Termination of Pregnancy (Amendment) Act, 2017 was enacted by the government of India with the intension of __________.

Consider the following L.P.P minimize \(z=x-7 y+190\) subject to \(x+y \leq 8, x+y \geq 4, x \leq 5, y \leq 5\) and \(x, y \geq 0\). Then which of the following is/are true?
(A) It's feasible region is unbounded
(B) It's feasible region is bounded
(C) It's feasible region has 5 corner polnts
(D) It's feasible region has 6 corner polnts
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What will be the minimum length of antenna required to transmit a radio signal of frequency 10 MHz ?

Identify " \(Y\) " in the following reaction:

A bar magnet held perpendicular to a uniform magnetic field experiences a torque \( T_1 \). By what angle should it be rotated to change the experienced torque to \( 0.5T_1 \)?

The electron in a hydrogen atom emits wavelengths \( \lambda_1, \lambda_2, \lambda_3, \lambda_4 \) in the following transitions (A), (B), (C), and (D), respectively. Arrange the transitions in the increasing order of emitted wavelengths:
(A) n = 3 to n = 2
(B) n = 4 to n = 3
(C) n = 4 to n = 2
(D) n = 2 to n = 1
Choose the correct answer from the options given below: