The major product formed when acetanilide undergoes bromination in presence of acetic acid is:

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Carbonyl compounds such as aldehydes, ketones, and carboxylic acids play an important role in the biochemical process of plants and animal kingdom.
Many aldehydes and ketones find applications in dye, perfumery and other industries.
The carbonyl carbon atom is \(s p^2\)-hybridized forming three sigma and one pi-bond with oxygen.
C-O bonds are polar bond due to high electronegativity of oxygen than carbon.
Hence the carbonyl carbon behaves as an electrophilic center and oxygen as a nucleophilic centre.
Primary and secondary alcohols yield aldehydes and ketones respectively upon oxidation with variety of oxidizing agents.
The boiling points of aldehydes and ketones differ from hydrocarbons and ethers.
Aldehydes and ketones undergo nucleophilic addition reaction due to presence of electrophilic carbonyl carbon.
Nucleophile and a proton add across the carbon oxygen double bond.
The alcohol which cannot be used to prepare carbonyl compound through oxidation is

Given below are the steps involved in the process of zone refining for removing impurities which are more soluble in the melt than solid state of the metal.
A. Impurities get concentrated at one end.
B. As the heater moves forward, the pure metal crystallises out of the melt left behind and the impurities pass to the next zone.
C. A mobile heater surrounding the rod of impure metal is fixed at its one end.
D. The end is cut off.
E. The molten zone moves along with the heater which is moved forward.
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The coordination compounds are of great importance. These compounds are widely present in the mineral, plants and animal world and are known to play many important functions in the area of analytical chemistry, metallurgy, biological systems, industry and medicine. For example, coordination compounds find use in many qualitative and quantitative chemical analysis. Some important metal extraction and purification make use of complex formation. Hardness of water can be estimated by stable complex formation of Ca\(^{2+}\) and Mg\(^{2+}\)
Impure nickel is converted to which of its complex to be decomposed to yield pure nickel?

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The coordination compounds are of great importance. These compounds are widely present in the mineral, plants and animal world and are known to play many important functions in the area of analytical chemistry, metallurgy, biological systems, industry and medicine. For example, coordination compounds find use in many qualitative and quantitative chemical analysis. Some important metal extraction and purification make use of complex formation. Hardness of water can be estimated by stable complex formation of Ca\(^{2+}\) and Mg\(^{2+}\)
Wilkinson catalyst used for hydrogenation of alkenes is a complex of ___________.

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The transition elements which give the greatest number of oxidation states occur in or near the middle of the series. Manganese, for example, exhibits all the oxidation states from +2 to +7. The lesser number of oxidation states at extreme ends stems from either too few electrons to lose or share (Sc, Ti) on too many d-electrons (hence fewer orbitals available in which to share electrons with others) for higher valence (Cu, Zn). Thus early in the series scandium (II) is virtually unknown and titanium (IV) is more stable than Ti (III) or Ti (II). At the other end, the only oxidation state of zinc is +2 (no d electrons are involved). The maximum oxidation states of reasonable stability correspond in value to the sum of the s- and d-electrons upto manganese (\(TiO_2, VVO^+, CrVIO_4^{2-}, MnVIIO_4\)) followed by a rather abrupt decrease in stability of higher oxidation states, so that the typical species to follow are \(Fe^{II,III}, Co^{II,III}, Ni^{II}, Cu^{I,II}, Zn^{II}\).
The variability of oxidation states, a characteristic of transition elements, arises out of incomplete filling of d-orbitals in such a way that their oxidation states differ from each other by unity, e.g. \(V^{II}, V^{III}, V^{IV}, V^{V}\). This is in contrast with the variability of oxidation states of non transition elements where oxidation states normally differ by a unit of two.
An interesting feature in the variability of oxidation states of the d-block elements is noticed among the groups (groups 4 through 10). Although in the p-block, the lower oxidation states are favoured by the heavier members (due to inert pair effect), the opposite is true in the groups of d-block. For example, in group 6, Mo(VI) and W(VI) are found to be more stable than Cr(VI). The Cr(VI) in the form of dichromate in acidic medium is a strong oxidising agent, whereas \(MoO_3\) and \(WO_3\) are not.
Low oxidation states are found when a complex compound has ligands capable of \(\pi\)-acceptor character in addition to the \(\sigma\)-bonding. For example, in \(Ni(CO)_4\) and \(Fe(CO)_5\), the oxidation state of nickel and iron is zero.
The elements giving minimum number of oxidation states are in extreme left and right in 3d series.
This is because :

The order of basic strength of amines in aqueous solution is :

The area of the region bounded by the parabola \(y^2=8 x\) and its latus rectum in the first quadrant, is

The amount of urea required to make a 500 mL solution of 0.25 molarity is
(Molar mass of Urea \(=60 g mol ^{-1}\) )

The figure shows a current loop having two circular arcs joined by two radial lines. If radius OA is 'a' and OD is 'b', the magnetic field at the centre O is.

The composition of Fehling solution A and Fehling solution B respectively are:

Match List-I (amino acid) with List-II (Characteristic Side Chain)

List-I  (amino acid)	List-II  (Characteristic Side Chain)
(A) Phenylalanine	(I) \(\left( CH _3\right)_2 CHCH _2-\)
(B) Leucine	(II) \(C _6 H _5 CH _2-\)
(C) Lysine	(III) \(CH _3- CH _2- CH \left( CH _3\right)-\)
(D) Isoleucine	(IV) \(H _2 N-\left( CH _2\right)_4-\)

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Composition of German silver alloy is :