CUET · CHEMISTRY · PYQ PAPER 2023
The cell \(Zn \left| Zn ^{2+}(1 M ) \| Cu ^{2+}(1 M )\right| Cu\) has \(E_{\text {cell }}^{\circ}=1.10 V\).
The cell is allowed to be completely discharged at 298 K .
The relative concentration of \(Zn ^{2+} / Cu ^{2+}\) is:
- A \(9.65 \times 10^4\)
- B Antilog \(24.8\)
- C \(37.7\)
- D \(10^{37.3}\)
Answer & Solution
Correct Answer
(D) \(10^{37.3}\)
Step-by-step Solution
Detailed explanation
\(E_{\text{cell}}^{\circ} = \frac{0.059}{n} \log K_c\) \(1.10 = \frac{0.059}{2} \log K_c\) \(\log K_c = \frac{1.10 \times 2}{0.059} = 37.288\) \(\frac{[Zn^{2+}]}{[Cu^{2+}]} = 10^{37.288} \approx 10^{37.3}\)
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