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CUET · CHEMISTRY · PYQ PAPER 2023

The cell \(Zn \left| Zn ^{2+}(1 M ) \| Cu ^{2+}(1 M )\right| Cu\) has \(E_{\text {cell }}^{\circ}=1.10 V\).
The cell is allowed to be completely discharged at 298 K .
The relative concentration of \(Zn ^{2+} / Cu ^{2+}\) is:

  1. A \(9.65 \times 10^4\)
  2. B Antilog \(24.8\)
  3. C \(37.7\)
  4. D \(10^{37.3}\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(10^{37.3}\)

Step-by-step Solution

Detailed explanation

\(E_{\text{cell}}^{\circ} = \frac{0.059}{n} \log K_c\) \(1.10 = \frac{0.059}{2} \log K_c\) \(\log K_c = \frac{1.10 \times 2}{0.059} = 37.288\) \(\frac{[Zn^{2+}]}{[Cu^{2+}]} = 10^{37.288} \approx 10^{37.3}\)
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