Standard reduction electrode potential of four metals A, B, C and D are as follows. The correct order of increasing strength of reducing power is :
(A) Metal A = +0.5 V
(B) Metal B = -3.0 V
(C) Metal C = -1.2 V
(D) Metal D = -2.3 V
Choose the correct answer from the options given below :

Interstitial transition metal compounds
(A) have higher melting points than those of pure metals.
(B) have more reactivity than those of pure metals.
(C) are non-stoichiometric compounds.
(D) formed when small atoms like H, C or N are trapped inside the crystal lattice of the metals.
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The \(C-O-H\) bond angle of alcohol is:

Match List-I with List-II

List-I (Aqueous Solutions)	List-II (Depression in freezing point (\(\Delta T_{f}\)) expression)
(A) \(0.2 \text{ mol } kg^{-1} Al_{2}(SO_{4})_{3}\)	(I) \(2K_{f}\)
(B) \(0.3 \text{ mol } kg^{-1} Na_{2}SO_{4}\)	(II) \(K_{f}\)
(C) \(1 \text{ mol } kg^{-1} KCl\)	(III) \(0.9K_{f}\)
(D) \(0.1 \text{ mol } kg^{-1} K_{3}[Fe(CN)_{6}]\)	(IV) \(0.4K_{f}\)

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Read the passage carefully and answer the Questions
Carbonyl compounds such as aldehydes, ketones, and carboxylic acids play an important role in the biochemical process of plants and animal kingdom.
Many aldehydes and ketones find applications in dye, perfumery and other industries.
The carbonyl carbon atom is \(s p^2\)-hybridized forming three sigma and one pi-bond with oxygen.
C-O bonds are polar bond due to high electronegativity of oxygen than carbon.
Hence the carbonyl carbon behaves as an electrophilic center and oxygen as a nucleophilic centre.
Primary and secondary alcohols yield aldehydes and ketones respectively upon oxidation with variety of oxidizing agents.
The boiling points of aldehydes and ketones differ from hydrocarbons and ethers.
Aldehydes and ketones undergo nucleophilic addition reaction due to presence of electrophilic carbonyl carbon.
Nucleophile and a proton add across the carbon oxygen double bond.
The alcohol which cannot be used to prepare carbonyl compound through oxidation is

A group 14 element is converted into n-type semiconductor by doping it with :

Arrange the following electrolytes in the increasing order of van't Hoff factor (i) for complete dissociation of solute.
(A) \([Co(NH_3)_6]Cl_3\)
(B) \(MgCl_2\)
(C) \(K_4[Fe(CN)_6]\)
(D) KCl
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Identify the correct statements among the following.
(A) At 0 K, the resistance of a semiconductor is infinite.
(B) In an n-type semiconductor, the electron concentration is approximately equal to the concentration of donor atoms.
(C) In p-type semiconductors, the acceptor levels lie near the conduction band.
(D) In n-type semiconductors, the charge carriers are both electrons and holes.
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The speed of the electron in \(n = 3\) orbit of \(He^+\) ion would be: (Given \(k = 9 × 10^9 \text{ N}⋅­m^2C^{-2}, e = 1.6 × 10^{-19} \text{ C}, h = 6.63 × 10^{-34} \text{ Js}\))

Choose the correct statement(s) from the following:
(A) With increasing reverse bias voltage, the barrier potential across the junction of p-n diode decreases.
(B) A p-type semiconductor can be obtained by doping Si or Ge with trivalent atoms.
(C) A rectifier rectifies dc voltages.
(D) Pure semiconductors are called extrinsic semiconductors.
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Read the passage carefully and answer the questions
Carbohydrates are naturally formed organic compounds from various plants. The common chemical formula, \(C _x\left( H _2 O \right)_y\), was considered as hydrates of carbon to derive the various carbohydrates. For instance, the general formula for glucose ( \(C _6 H _{12} O _6\) ) easily fits into the above formula. Carbohydrates also called saccharides are classified on the basis of their behavior towards hydrolysis. Monosaccharides cannot be hydrolyzed further to simpler units of polyhydroxy aldehyde or ketones. About 20 monosaccharides are known to occur in nature. Carbohydrates that yield large number of monosaccharide units are called polysaccharides. Amino acids contain ( \(- NH _2\) ) and ( - COOH ), which can be classified in various forms. Proteins are polymers of alpha amino acids which are connected to each other by a peptide bond or peptide linkage. When a native protein is subjected to physical change, its globules unfold and helix get uncoiled and the protein loses its biological activity. The protein is said to be denaturated.
The two monosaccharides units are joined together through which linkage ?

Arrange the following steps of replication of retrovirus in correct sequence
A. Incorporation of viral DNA into host genome.
B. Formation of viral DNA by reverse transcription.
C. Infection of normal cell by virus and introduction of viral RNA into host
D. Production of new viral RNA by infected cells.
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\(\int \frac{\cos x-\sin x}{1+\sin 2 x} d x\) is equal to