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Werner in 1898, propounded his theory of coordination compounds. In coordination compounds metals show two types of linkages (valences)-primary and secondary. The primary valences are normally ionisable and are satisfied by negative ions. The secondary valences are non-ionisable. These are satisfied by neutral molecules or negative ions. The secondary valence is equal to the coordination number and is fixed for a metal. The ions or group bound by the secondary linkages to the metal have characteristic spatial arrangements corresponding to the different coordination numbers. Both double salts as well as complexes are formed by the combination of two or more stable compounds in stoichiometric ratio. However, they differ in the fact that double salts such as carnallite, Mohr's salt, potash alum etc. dissociate into simple ions completely when dissolved in water. But complex ions do not dissociate completely into simple ions.
Which of the following statement is correct as per Werner theory?

\(0.1\) M aqueous solution of the following salts were prepared. Their conductivity values were measured at \(25\circ C\). Which of the following will possess least conductivity at \(25\circ C\)?

For a fixed volume of liquid solvent, the solubility of a gaseous solute depends upon......
(A) Nature of the gas.
(B) Pressure at constant temperature.
(C) Temperature at constant pressure.
(D) Nature of solvent.
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On heating, \(\left[ Ti \left( H _2 O \right)_6\right] Cl _3\) becomes colorless because \(\backslash\) ldots \(\backslash\) ldots \(\backslash\) ldots

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P block elements are placed in groups 13 to 18 of the periodic table. Their valence shell electronic configuration is \(ns^2 np^{1-6}\). Group 16 of the p block elements are known as the group of chalcogens having \(ns^2 np^4\) as their general electronic configuration. They exhibit number of oxidation states but the stability of \(- 2\) oxidation state decreases down the group. They are sometimes also known as group of chalcogens as the name is derived from the Greek word for brass and points to the association of sulphur and its congeners with copper. Their ionisation enthalpy decreases down the group. Oxygen shows anomalous behaviour due to its small size and high electronegativity.
Match the oxidation state of phosphorous in the following compounds to their counter parts in List II.

List - I (Compounds)	List - II (Oxidation States)
(A) \(H _3 PO _2\)(Hypophosphorous acid)	(I) +3
(B)\(H _4 P _2 O _6\)(Hypophosphoric acid)	(II) +5
(C) \(H _3 PO _3\)(Phosphorous acid)	(III) +1
(D)\(H _3 PO _4\)(Orthophosphoric acid)	(IV) +4

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Choose the incorrect statements from the following :
(A) The dipole moment of cyclohexyl chloride is smaller than chlorobenzene.
(B) Alkyl halides are immiscible with water.
(C) The dipole moment of methyl chloride is higher than that of methyl fluoride.
(D) Chloroform doesn't undergo aerial oxidation in the presence of light
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Nearly all the transition elements display typical metallic properties such as high tensile strength, ductility, malleability, high thermal and electrical conductivity and metallic lustre. The transition metals (with the exception of Zn, Cd and Hg) are very hard and have low volatility. Their melting and boiling points are high. They have high enthalpies of atomization. lons of the same charge in a given series show progressive decrease in radius with increasing atomic number. However, the variation within a series is quite small. The filling of 4f before 5d orbital results in a regular decrease in atomic radii called Lanthanoid contraction which essentially compensates for the expected increase in atomic size with increasing atomic number. The net result of the lanthanoid contraction is that the second and the third d series exhibit similar radii (e.g., Zr 160 pm, Hf 159 pm) and have very similar physical and chemical properties. There is an increase in ionisation enthalpy along each series of the transition elements from left to right. The first ionisation enthalpy, in general, increases, but the magnitude of the increase in the second and third ionisation enthalpies for the successive elements, is much higher along a series. One of the notable features of a transition elements is the great variety of oxidation states these may show in their compounds.
Atomic number of Fe, Co, Ni and Cu are 26, 27, 28 and 29 respectively. Which among them is expected to possess the highest value for the second ionization enthalpy?

Observe the given figures and answer the question

Identify the statements which hold true for Miller's experiment:
(A) He created an electric discharge in a closed flask containing CH4, N2, NH3 and water vapour at 1200°°C
(B) He created electric discharge in a closed flask containing CH4, N2, NH3 and water vapour at 800°C
(C) He observed the formation of amino acids only
(D) He observed the formation of amino acids, sugars and fats
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Arrange the given steps for sewage treatment plant in correct sequence?
(A) Formation of flocs
(B) Pumping of sludge into anaerobic sludge digester
(C) Filtration and sedimentation
(D) Reduction in BOD by biological treatment
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If \(\vec{a}=5 \hat{i}-\hat{j}-3 \hat{k} \& \vec{b}=\hat{i}-3 \hat{j}+5 \hat{k}\) the angle between \(\vec{a}+\vec{b}\) and \(\vec{a}-\vec{b}\) is:

Match List-I with List-II

List - I	List - II
A. Activation Energy	I. Difference in the energy of activated complex and reactants
B. Threshold Energy	II. Minimum Energy possessed by reactant molecules to form effective collisions
C. Heat of Reaction	III. Negative for exothermic reaction
D. Role of a catalyst	IV. To give new path of reaction

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If \(\mathbb{Z}\) and \(\mathbb{R}\) set of integers and set of real numbers respectively, then match List I with List II.

List - I	List - II
(A) \(5 x-3<3 x+1, x \in \mathbb{Z}\)	(I) \(x \in(-\infty,-3)\)
(B) \(3 x+17 \leq 2(1-x), x \in \mathbb{R}\)	(II) \(x \in(-\infty,-1)\)
(C) \(13 x+17<2(1-x), x \in \mathbb{R}\)	(III) \(\{\ldots,-4,-3, \ldots, 0,1\}\)
(D) \(\frac{2 x+3}{5}-2>\frac{3(x-2)}{5}, x \in \mathbb{Z}\)	(IV) \(\{\ldots,-4,-3,-2\}\)

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If \(x^2-y^2=t-\frac{1}{t}\), and \(x^4+y^4=t^2+\frac{1}{t^2}\), then which of the following is correct?