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The coordination compounds are of great importance. These compounds are widely present in the mineral, plants and animal world and are known to play many important functions in the area of analytical chemistry, metallurgy, biological systems, industry and medicine. For example, coordination compounds find use in many qualitative and quantitative chemical analysis. Some important metal extraction and purification make use of complex formation. Hardness of water can be estimated by stable complex formation of Ca\(^{2+}\) and Mg\(^{2+}\)
From which coordination complex, gold is recovered by reducing this complex with Zn ?

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Haloalkanes undergo nucelophilic substitution reactions owing to the polarity of C X bond. The nucleophile reacts with the haloalkane on the carbon possessing a partial positive charge holding the halogen atom. The halogen atom \(X\) is replaced by a nucleophile. Depending on the kinetics and mode of bond breaking, the mechanism can be either SN1 or SN2 reaction. The rate of SN1 reaction is governed by the stability of carbocation and in SN2 reaction, the rate of reaction is governed by steric factor. Chirality is the main factor in both SN1and SN2. In SN1 reaction, the chirality of alkyl halide is accompanied by racemization of the product, while in SN2 reaction, the product is characterized by inversion of configuration. The structure of alkyl halide and the nature of the solvent also governs the mechanism of the substitution.
What is chiral carbon ?

For a non ideal solution exhibiting positive deviation:
A. The vapour pressure is lower than that predicted by Raoult's law
B. The vapour pressure is higher than that predicted by Raoult's law.
C. The interaction at the molecular level are weaker than in the pure state.
D. The interaction at the molecular level are stronger than in the pure state.
E. Mixture of chloroform and acetone is a suitable example.
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In the following statements the in correct statement is :

Excess of Lead from human body can be removed by using which of the following chelating agents?

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Kinetic studies not only help us to determine the rate of a chemical reaction but also describe the conditions by which the reaction rates can be altered.
The factors such as concentration, temperature, pressure and catalyst affect the rate of a reaction.
The speed of a reaction or the rate of a reaction can be defined as the change in concentration of a reactant or product in unit time.
Rate \(=k[A]^x[B]^y\)
Here \(k\) is the rate constant
\(x+y\) gives the overall order of a reaction, whereas \(x\) and \(y\) represent the order with respect to the reactants \(A\) and \(B\), respectively.
The order of a reaction which does not exist is

\(s p^3\) hybridization leads to ______________

Which of the following is correct about RNA ?
(A) Unstable and mutates slower
(B) Unstable and mutates faster
(C) Stable and mutates faster
(D) Stable and mutates slower
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The voltage sensitivity of a voltmeter can be increased by :
(A) decreasing the resistance of the voltmeter
(B) increasing the resistance of the voltmeter
(C) decreasing the torsional constant of spring
(D) increasing the number of turns of the coil
(E) taking a strong permanent magnet
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An insect moves along the ellipse \(\frac{x^2}{16}+\frac{y^2}{4}=1\), when the rate of change of abscissa is 4 times that of ordinate, then the insect lies in the quadrant:
A. \(I or II\)
B. \(III or IV\)
C. \(II or III\)
D. \(II or IV\)
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Which one of the following techniques is used for the separation of DNA fragments?

If \(A\) is a square matrix such that \(A^2=A\), then \((I+A)^3-8 A\) is equal to:

Which of the following is true for species area relationship equation log S = log C + Z log A