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CUET · CHEMISTRY · PYQ PAPER 2025

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The chemical reactions proceed at different rates which depend on various factors like concentration, temperature, etc. Rate law is an expression which relates the rate of reaction with concentration of various reacting species in the reaction. For a first order reaction, the concentration of the reactant after time \(t\) is related with its initial concentration by the relation, \(C=C_0 e^{-k t}\). The rate constants for different orders have different expressions. For a first order reaction, \(k=\frac{2.303}{t} \log \frac{a}{a-x}\), where \(a\) is the initial concentration and \(x\) is the extent of reaction.
Which plot is linear with negative slope for a first order reaction

  1. A \(k\) vs \(\ln [ C ]\)
  2. B \(\ln k\) versus \(\ln C\)
  3. C ln \(k\) versus time
  4. D \(\ln [C]\) versus time
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Answer & Solution

Correct Answer

(D) \(\ln [C]\) versus time

Step-by-step Solution

Detailed explanation

\(\ln C = \ln C_0 - k t\) Plot of \(\ln [C]\) versus time is linear with slope \(-k\).
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