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CUET · CHEMISTRY · PYQ PAPER 2025

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Molar conductivity \(\left(\Lambda_m\right)\) of a solution at a given concentration (c) is the conductance of volume, V of solution, containing one mole of electrolyte kept between the two electrodes with area of cross-section A and at a distance of unit length. It increases
with the decrease in concentration and when the concentration approaches zero, the molar conductivity is called limiting molar conductivity \(\left(\Lambda_m^0\right)\). For a strong electrolyte, \(\Lambda_m\) increases linearly with dilution and is given by \(\Lambda_m=\Lambda_m^0-A c^{1 / 2}\). The value of the constant A for a given solvent depends on the type of electrolyte along with temperature. According to Kohlrausch law, the value of \(\left(\Lambda_m^0\right)\) for an electrolyte is \(\Lambda_m^0=\nu_{+} \lambda_{+}^0+\nu_{-} \lambda_{-}^0\), where \(\nu_{+}\)and \(\nu_{-}\) are the number of cations and anions, respectively, per
molecule of the electrolyte and \(\lambda_{+}^0\) and \(\lambda_{-}^0\) are limiting molar conductivities of cation and anion, respectively. Kohlrausch law
finds many applications, like determining the solubility of a sparingly soluble salt, determining the degree of dissociation \(\left(\Lambda_m / \Lambda_m^0\right)\), and the dissociation constant of a weak electrolyte.
The unit of constant A is :

  1. A S cm2 mol-1.
  2. B S cm2 mol-1 L-1.
  3. C S cm2 mol-3/2 l-1/2.
  4. D S cm2 mol-1/2 L-1/2.
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(C) S cm2 mol-3/2 l-1/2.

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S cm2 mol-3/2 l-1/2.
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