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CUET · CHEMISTRY · PYQ PAPER 2023

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Kinetic studies not only help us to determine the rate of a chemical reaction but also describe the conditions by which the reaction rates can be altered. The factors such as concentration, temperature, pressure and catalyst affect the rate of a reaction.
The speed of a reaction or the rate of a reaction can be defined as the change in concentration of a reactant or product in unit time.
Rate \(=k[A]^{\text {a }}[B]^{\text {y }}\)
Here \(k\) is the rate constant
\(x+y\) gives the overall order of a reaction, whereas \(x\) and \(y\) repreeent the order with respect to the reactants \(A\) and \(B\), respectively.
Table: Initial rate of formation of NO 2
S No.Initial [NO]/mol L-1Initial [O2]/mol L-1Initial rate of formation of NO2/mol L-1s-1
1.0.300.30.096
2.0.600.30.384
3.0.300.60.192
4.0.600.60.768

  1. A Rate of reaction \(=k[ NO ]^2\left[ O _2\right]\)
  2. B Rate of reaction \(=k[ NO ]\left[ O _2\right]^2\)
  3. C Rate of reaction \(=k[ NO ]^2\left[ O _2\right]^2\)
  4. D Rate of reaction \(=k[ NO ]\left[ O _2\right]\)
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Answer & Solution

Correct Answer

(A) Rate of reaction \(=k[ NO ]^2\left[ O _2\right]\)

Step-by-step Solution

Detailed explanation

\(\text{Order with respect to NO: } \frac{\text{Rate}_2}{\text{Rate}_1} = \left(\frac{[\text{NO}]_2}{[\text{NO}]_1}\right)^{\text{x}}\) \(\frac{0.384}{0.096} = \left(\frac{0.60}{0.30}\right)^{\text{x}}\) \(4 = (2)^{\text{x}} \Rightarrow x = 2\)…
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