Read the passage carefully and answer the questions
Carboxylic acids are the organic compounds which comprise of carboxyl functional group, -COOH. These are generally found in nature, some higher members are known as fatty acids as they occur in natural fats as esters of glycerol. They can be prepared from oxidation of alcohols and aldehydes, hydrolysis of nitriles and amides and Grignard reagents. They are stronger acids than simple phenols and alcohols. but weaker than mineral acids. Substituents affect the acidity of aliphatic and aromatic carboxylic acids. They undergo reactions involving cleavage of -OH and C-OH bond. Carboxylic acids having an alpha hydrogen get halogenated in the presence of red phosphorus to form alpha halo carboxylic acids. The reaction is known as Hell Volhard Zelinsky reaction. Besides these aromatic carboxylic acids undergo electrophilic substitution reactions. They are versatile and are employed in the manufacture of various useful compounds. For example, methanoic acid is used in rubber, textile, dyeing, leather and electroplating industries. Higher fatty acids are used in the manufacture of soaps and detergents. Esters of Benzoic acid are used in perfumery.
Which carboxylic acid will not undergo HVZ reaction?

Which of the statements below are correct?
A. Actinoid contraction is greater than lanthanoid contraction.
B. The magnetic property of the actinoids are more complex than those of the lanthanoids.
C. Actinoid contraction taking place due to poor shielding by 5f electrons.
D. Actinoid contraction taking place due to poor shielding by 6f electrons.
Choose the correct answer from the options given below:

Number of hydrogen bond formed between adenine and thymine to connect each other is /are

Read the passage carefully and answer the questions:
The degeneracy of the \(d\) orbitals has been removed due to ligand electron-metal electron repulsions in the octahedral complex to yield three orbitals of lower energy, \(t_2\), set and two orbitals of higher energy, \(e_g\) set. This splitting of the degenerate levels due to the presence of ligands in a definite geometry is termed as crystal field splitting and the energy separation is denoted by \(\Delta_0\). Thus energy of the two \(e_g\), orbitals will increase by \((3 / 5) \Delta_0\) and that of three \(t_{2 g}\) will decrease by \((2 / 5) \Delta_0\). The crystal field splitting \(\Delta_0\) depends upon the field produced by the ligand and charge on the metal ion. Some ligands are able to produce strong fields, in which case the splitting will be large, whereas others produce weak fields and consequently result in small splitting of \(d\) orbitals. Relative magnitude of crystal field splitting energy \(\Delta_0\) and pairing energy, \(P\) (energy required for electron pairing in a single orbital) determine the formation of low spin ( \(\Delta_0>P\) ) or high spin ( \(\Delta_0<P\) ) complex. In tetrahedral coordination entity formation, the \(d\)-orbital splitting is inverted and is smaller as compared to the octahedral field splitting. The crystal field theory attributes the colour of the complex to \(d-d\) transition of the electron. The colour of the coordination compounds depends on the crystal field splitting. In the absence of ligand, crystal field splitting does not occur and hence the substance is colourless.
Choose the correct statement from the following:

The specific rate constant of a first order reaction depends on the

Match List-I with List-II

List-I (Structure of Protein)	List-II (Function)
(A) Primary Structure	(I) Gives rise to Fibrous and Globular Proteins
(B) Secondary structure	(II) Sequence of amino acid
(C) Tertiary Structure	(III) shape of polypeptide chain
(D) Quaternary Structure	(IV) Spatial arrangement of sub-units

Choose the correct answer from the options given below:

Which one of the following correctly represents the concentration term 'ppm'?

Identify one of the given factors which does not affect Hardy-Weinberg equilibrium.

The percentage dissociation of 0.1 M AgI solution having a resistance of 100 \(\Omega\) in an electrolytic cell with cell constant 4 \(\text{cm}^{-1}\) is:
\(\lambda_{\text{m}}^{\circ}\) \(\left( AgNO _3\right)\) = 8000 \(\Omega^{-1}\text{cm}^2\text{mol}^{-1}\)
\(\lambda_{\text{m}}^{\circ}\) \(\left( KNO _3\right)\) = 10500 \(\Omega^{-1}\text{cm}^2\text{mol}^{-1}\)
\(\lambda_{\text{m}}^{\circ}\) (KI) = 9500 \(\Omega^{-1}\text{cm}^2\text{mol}^{-1}\)

If \(, A=\left[\begin{array}{ll}x & 3 \\ 2 & 4\end{array}\right], B=\left[\begin{array}{ll}2 & 3 \\ y & 3\end{array}\right]\) and,\(C=\left[\begin{array}{ll}z & 1 \\ 8 & 2\end{array}\right]\) are singular matrices then :
(A) \(x>y\)
(B) \(y>z\)
(C) \(z>x\)
(D) \(x \neq y \neq z\)
Choose the correct answer from the options given below :

The value(s) of K, for which the system of linear equations 2x + y + x = 1, x + Ky - x = \(\frac{3}{2}\) and 3y - 5x = 9 does not possess a unique solution is

Match List-I with List-II

List-I	List-II
(A) The maximum value of \(f(x)=\sin (3 x)+6\)	(I) 2
(B) The maximum value of \(f(x)=-|x+2|+4\)	(II) 5
(C) The maximum value of \(f(x)=(3 x+1)^2+5\)	(III) 7
(D) The maximum value of \(f(x)=2 \cos x+4\)	(IV) 4

Choose the correct answer from the options given below:

Read the Passage carefully and answer the questions
When a ligand is bound to a metal ion through a single donor atom, it is said to be a unidentate ligand but when it bind through two donor atoms, then it is said to be didentate ligand and when several donor atoms are present in a single ligand, it is said to be a polydentate ligand. When a dior polydentate ligand uses its two or more donor atoms simultaneously to bind a single metal ion, it is said to be a chelate ligand. The number of such ligating groups is called the denticity of the ligand. ligand which has two different donor atoms and either of the two ligetes in the complex is called ambidentate ligands. The number of ligand donor atoms to which the metal is directly bonded, is called coordination number of the metal ion in the complex. Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic and in which a metal is bound to more than one kind of donor groups are known as heteroleptic complexes.
Which among the following is an ambidentate ligand?