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Aldehydes, carboxylic acids and ketones are widespread in the animal and plant kingdoms.
They play a pivotal role in various biochemical processes of life. Their presence in nature adds fragrance and flavor. These compounds are widely used in food products, pharmaceuticals, paints, resins and other important product industries. These compounds are prepared by various laboratory methods, which mainly include oxidation, formylation, acylation and reduction. Due to the polar nature of the carbonyl group in aldehydes and ketones, they can exhibit different reactions like nucleophilic addition. They do exhibit redox and various condensation reactions which lead to the formation of various important compounds. On the other hand, the carboxylic acids are mainly prepared by oxidation and hydrolysis of different compounds. The carboxylic acid consists of a carbonyl group and the hydroxy group (attached to the carbonyl carbon atom). This makes it possible for the carboxylic acid to participate in various chemical reactions which involve cleavage of the C-OH bond and the O_H bond along with the reactions involving the complete -COOH group.
Identify the final product (X) of the chemical reaction obtained from the following transformation :

\(CH_3CH_2COCH_3 \xrightarrow{Y} CH_3CH_2CH_2CH_3\) The reagent Y is:

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When a ligand is bound to a metal ion through a single donor atom, it is said to be a unidentate ligand but when it bind through two donor atoms, then it is said to be didentate ligand and when several donor atoms are present in a single ligand, it is said to be a polydentate ligand. When a dior polydentate ligand uses its two or more donor atoms simultaneously to bind a single metal ion, it is said to be a chelate ligand. The number of such ligating groups is called the denticity of the ligand. ligand which has two different donor atoms and either of the two ligetes in the complex is called ambidentate ligands. The number of ligand donor atoms to which the metal is directly bonded, is called coordination number of the metal ion in the complex. Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic and in which a metal is bound to more than one kind of donor groups are known as heteroleptic complexes.
Which of the following is a chelate complex?

A reaction takes 30 minutes to complete 50\(\%\) of the reaction and takes 45 minutes to complete 75\(\%\) of the reaction. The order of the reaction is :

With reference to Arrhenius equation \(k=A e^{-E_a / R T}\)

Which of the following have lowest value of pK, in their aqueous solution?

The degree of dissociation ( \(\alpha\) ) of a weak electrolyte \(A_x B_y\) is related to the van't Hoff factor (i) by the expression:

Amniocentesis should not be used for:

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DRUGS AND ALCOHOL ABUSE
The drugs, commonly abused are opioids, cannabinoids, and coca alkaloids. Opioids are the drugs, which bind to specific opioid receptors present in our central nervous system and gastrointestinal tract. Heroin, commonly called smack is chemically diacetylmorphine which is a white, odourless, bitter crystalline compound. Cannabinoids are a group of chemicals, which interact with cannabinoid receptors present principally in the brain. Natural cannabinoids are obtained from the inflorescences of the plant Cannabis sativa. The flower tops, leaves and the resin of cannabis plant are used in various combinations to produce marijuana, hashish, charas and ganja. Generally taken by inhalation and oral ingestion, these are known for their effects on cardiovascular system of the body. It interferes with the transport of the neuro-transmitter dopamine. Cocaine, commonly called coke or crack is usually snorted. It has a potent stimulating action on central nervous system, producing a sense of euphoria and increased energy. Excessive dosage of cocaine causes hallucinations. Other well-known plants with hallucinogenic properties are Atropa belladona and Datura. These days cannabinoids are also being abused by some sportspersons. Drugs like barbiturates, amphetamines, benzodiazepines, and other similar drugs, that are normally used as medicines to help patients cope with mental illnesses like depression and insomnia, are often abused. Morphine is a very effective sedative and painkiller, and is very useful in patients who have undergone surgery. Several plants, fruits and seeds having hallucinogenic properties have been used for hundreds of years in folk-medicine, religious ceremonies and rituals all over the globe.
Heroine (Smack) which is extracted from the latex of poppy plant is chemically called:

The composition of biogas is -

Answer the question on the basis of passage given below:
Proteins are the polymers of about twenty different a-amino acids which are linked by peptide bonds. Proteins perform various structural and dynamic functions in the organisms. Proteins which contain only a-amino acids are called simple proteins. The secondary or tertiary structure of proteins get disturbed on change of pH or temperature and they are not able to perform their functions. This is called denaturation of proteins. Enzymes are biocatalysts which speed up the reactions in biosystems. Vitamins are accessory food factors required in the diet. They are classified as fat soluble (A, D, E and K) and water soluble (B group and C). Deficiency of vitamins leads to many diseases. Nucleic acids are the polymers of nucleotides which in turn consist of a base, a pentose sugar and phosphate moiety.Nucleic acids are responsible for the transfer of characters from parents to offsprings. There are two types of nucleic acids DNA and RNA. DNA contains a five carbon sugar molecule called 2-deoxyribose whereas RNA contains ribose.
During denaturation of proteins:

A wheel with 8 metallic spokes each 50 cm long is rotated with a speed of 120 rev/min in a plane normal to the horizontal component of the earth's magnetic field. The earth's magnetic field is \( 0.4 \text{ G} \). Calculate the emf induced between the axle and the rim.

If \(\vec{a}, \vec{b}\), and \(\vec{c}\) are unit vectors such that \(\vec{a}+\vec{b}+\vec{c}=\overrightarrow{0}\), then value of \(\vec{a} \cdot \vec{b}+\vec{b} \cdot \vec{c}+\vec{c} \cdot \vec{a}\) is :