Reaction of aniline with conc. \(HNO _3\) and conc. \(H _2 SO _4\) at 298 K will produce \(47 \%\) of:

The IUPAC name of the following compound is

Match List-I with List-II

List-I (Aqueous Solutions)	List-II (Depression in freezing point (\(\Delta T_{f}\)) expression)
(A) \(0.2 \text{ mol } kg^{-1} Al_{2}(SO_{4})_{3}\)	(I) \(2K_{f}\)
(B) \(0.3 \text{ mol } kg^{-1} Na_{2}SO_{4}\)	(II) \(K_{f}\)
(C) \(1 \text{ mol } kg^{-1} KCl\)	(III) \(0.9K_{f}\)
(D) \(0.1 \text{ mol } kg^{-1} K_{3}[Fe(CN)_{6}]\)	(IV) \(0.4K_{f}\)

Choose the correct option:

Read the passage carefully and answer the questions
The osmotic pressure is one of the four colligative properties which depends on the number of particles of solute in the solution, irrespective of their nature. The osmotic pressure is equal to the product of concentration, gas constant and temperature. It is the most commonly used property for the determination of the molar mass of biomolecules. In many situations, the molecules get dissociated or associated when they are dissolved in a solvent, thereby changing the number of molecules in the solution. As a result, an abnormal molecular mass is obtained. The extent of dissociation or association is given by van't Hoff factor (i), which is the ratio of normal molar mass to abnormal molar mass. It is related with the degree of association or ionization. The introduction of van't Hoff factor in the osmotic pressure equation modifies the equation.
Which one of the following has minimum osmotic pressure at 298 K ?

Read the following passage given below and answer the question.
Production of electricity by thermal plants is not very efficient method. It is now possible to make cells in which reactants are fed continuously to the electrodes and products are also removed continuously. One of the most successful fuel cells is hydrogen fuel cell.
In Hydrogen fuel cell, which gas is undergoing oxidation?

The correct statement (s) for cubic close packed (ccp) three dimensional structure are :
(A) The number of the neighbours of an atom present in the top most layer is 12.
(B) The efficiency of atom packing is \(74\%\).
(C) The number of octahedral and tetrahedral voids per atom are 1 & 2, respectively.
(D) The unit cell edge length is \(2\sqrt{2}\) times the radius of the atom.
(E) The metals like Be, Cd, Mg, Zn have cubic close packed (ccp) structure.
Choose the correct answer from the options given below :

For a complex reaction, the order of reaction is equal to:

Let \(X\) denote the number of tails in two tosses of a coin. If the mean and the variance of \(X\) are \(\mu\) and \(\sigma^2\) respectively, then \(\mu+\sigma^2\) is equal to:

Which one of the following diseases can be treated by human protein (a -1-
antitrypsin) produced by transgenic animals?

Read the passage carefully and answer the Questions
In the formation of coordination complexes, if the inner \(d\) orbital \((n - 1)d\) is used in hybridisation, the complex, is called an inner orbital or low spin or spin paired complex. And if it uses outer \(d\) orbital \((nd)\) in hybridisation (like \(sp^3d^2\)), it is called outer orbital or high spin or spin free complex. The degeneracy of the \(d\) orbitals has been removed due to ligand electron-metal electron repulsions in the complex. This splitting of the degenerate levels due to the presence of ligands in a definite geometry is termed as crystal field splitting. For coordination complexes, the magnetic moment is determined by the number of unpaired electrons and is calculated by using the 'spin-only' formula, \(\mu = \sqrt{n(n+2)}\) where \(n\) is the number of unpaired electrons and \(\mu\) is the magnetic moment in units of Bohr magneton \((BM)\). The coordination compounds are of great importance. These compounds are widely present in the mineral, plant and animal worlds and are known to play many important functions in the area of analytical chemistry, metallurgy, biological systems, industry and medicine.
Which of the following metals belongs to Wilkinson catalyst?

A potential difference of 6 V is applied across a conductor of length 12 cm. If the mobility of electrons is \( 5.6 \times 10^{-6} \text{ m}^2/\text{V}\cdot\text{s} \), their drift velocity will be:

Answer the question on the basis of passage given below:
In the periodic table, the d-block contains the elements of group \(3\) to \(12\). The d-orbitals are progressively filled in each of the four long periods. The elements of d block referred as transition metals have partly filled d orbitals and exhibit certain characteristic properties such as variety of oxidation states, formation of coloured ions, act as catalyst and show paramagnetic behaviour.
The two inner transition metals series \(4f\) and \(5f\) are known as Lanthanoids and Actinoids respectively. The lanthanoids resemble one another more closely as compared to ordinary transition elements in any series.
In context of the Lanthanoids, which of the following statements is/are NOT correct?
A. There is a gradual decrease in the radii of the members with increasing atomic number in the series
B. Availability of \(4f\) electrons results in the formation of compounds in \(+4\) oxidation state for all the members of the series
C. Because of similar properties, the separation of lanthanoids is not easy
D. \(La(OH)_3\) is least basic among hydroxides of lanthanoids
E. Ce can act as an oxidising agent
Choose the correct answer from the options given below:

For a series LCR circuit, \( R = X_L = 3X_C \). The impedance of the circuit and the phase difference between voltage V and current I, respectively, will be: