p-block elements are placed in groups 13 to 18 of the periodic table. Group 15 is nitrogen family.
Nitrogen makes various compounds like \(NH _3, HNO _3, N_2 O , NO _2\) etc. Phosphorus exists in the form of white and red phosphorus. White phosphorus glows in dark. \(PH _3\) gas is used as smoke screen. Group 16 is called oxygen family. Dry air contains \(21\% O_2\) gas by volume. Combined sulphur exists as sulphates such as gypsum, epsome salt, baryte etc. The allotropic forms of sulphur are Rhombic and monoclinic sulphur. \(S_2\) is paramagnetic like \(O_2\) and it stable at high temperature.
Group 17 is Halogen family. \(F_2\) is highly reactive, \(Cl _2\) is greenish yellow gas. Both \(SO _2\) and \(Cl _2\) are used for bleaching. Group 18 is Noble gas family but some noble gases also form compounds.
Complete hydrolysis of \(XeF _6\) gives HF and \(XeO _3\) as main products.
At elevated temperature \((\sim 1000 K)\) the dominant form of sulphur is :

Match List-I with List-II

List-I (Components of binary solution)	List-II (Deviation from Raoult's Law)
(A) Ethanol and water	(I) Positive
(B) Chloroform and acetone	(II) No deviation
(C) n-Hexane and n-heptane	(III) Negative
(D) Carbon disulphide and acetone	(IV) Large positive
(D) Carbon disulphide and acetone	(IV) Large positive

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The order of reaction with rate law expression \(\frac{d[R]}{dt} = -k\) is:

In a pure crystal, the lattice point cannot be occupied by:

A catalyst increases the rate of reaction by:

Match List I with List II

LIST - I	LIST - II
A. Mathematical expression for rate of reaction	I. rate constant
B. Rate of reaction for zero order reaction is equal to	II. rate law
C. Unit of rate constant for zero order reaction is same as that of	III. order of slowest step
D. Order of a complex reaction is determined by	IV. rate of reaction

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Which of the following statements is/are incorrect?

Which of the following statements best describe the temperature dependence of resistances of Cu and Si in the temperature range 27° to 127°C.

Which of the following properties are related to the complex \(\left[ Fe \left( H _2 O \right)_6\right]^{3+}\) ?
(A) Paramagnetic
(B) Number of unpaired electrons are five
(C) \(d ^2 sp ^3\) hybridisation
(D) \(H _2 O\) is a strong field ligand
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The karyotype in klinefelter's syndrome is:

Read the following passage carefully and answer the given questions.
Insulin consists of two short polypeptide chains- chain A and chain B, that are linked together by disulphide bridges. Some strains of Bacillus thuringiensis produce proteins that kill certain insects such as lepidopterans, coleopterans and dipterans. Bt toxin protein is converted into an active form of toxin due to the alkaline pH of the gut which solubilise the crystals. Transgenic animals that produce useful biological products can be created by the introduction of the portion of DNA (or genes) which codes for a particular product such as human protein (alpha-1-antitrypsin) used to treat emphysema. Plants, bacteria, fungi and animals whose genes have been altered by manipulation are called Genetically Modified Organisms (GMO). GM plants have been useful in many ways. Genetic modification has: (i) made crops more tolerant to abiotic stresses. (ii) reduced reliance on chemical pesticides (pest-resistant crops). (iii) helped to reduce post harvest losses. (iv) increased efficiency of mineral usage by plants (this prevents early exhaustion of fertility of soil). (v) enhanced nutritional value of food.
Transgenic animals that produce useful biological products such as human protein (alpha-1-antitrypsin) used to treat the disorder:

Match List-l with List-ll

List-l (Techniques)	List-II (Features)
(A) Bioprocess engineering	(I) Use of bio resources without proper authorisation
(B) Somatic hybridisation	(II) Correction of gene defect
(C) Gene therapy	(III) Fusion of protoplasts from two different organisms
(D) Biopiracy	(IV) Maintenance of sterile ambiance for microbial growth

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Answer the question on the basis of passage given below:
Adsorption is the phenomenon of attracting and retaining the molecules of a substance on the surface of a solid resulting into a higher concentration on the surface than in the bulk. The substance adsorbed is known as adsorbate and the substance on which adsorption takes place is called adsorbent. In physisorption adsorbate is held to the adsorbent by weak van der Waals forces and in chemisorption by strong chemical bond.
In coagulation of a positive sol, the flocculating power will be in the order:
A. \(PO _4^{3-}\)
B. \(Cl ^{-}\)
C. \([ Fe ( CN )]^{3-}\)
D. \(SO _4^{2-}\)
Choose the correct answer from the options given below: