Match the elements given in List-I with electronic configuration given in List-II

List - I (Element)	List - II (Electronic configuration)
(A) Cerium	(I) \([ Xe ] 4 f^{f 12} 6 s^2\)
(B) Erbium	(II) \([ Rn ] 5 f^7 6 d^1 7 s^2\)
(C) Uranium	(III) \([ Xe ] 4 f^1 5 d^1 6 s^2\)
(D) Curium	(IV) \([ Rn ] 5 f^3 6 d^1 7 s^2\)

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Read the passage carefully and answer the Questions
Carbonyl compounds such as aldehydes, ketones, and carboxylic acids play an important role in the biochemical process of plants and animal kingdom.
Many aldehydes and ketones find applications in dye, perfumery and other industries.
The carbonyl carbon atom is \(s p^2\)-hybridized forming three sigma and one pi-bond with oxygen.
C-O bonds are polar bond due to high electronegativity of oxygen than carbon.
Hence the carbonyl carbon behaves as an electrophilic center and oxygen as a nucleophilic centre.
Primary and secondary alcohols yield aldehydes and ketones respectively upon oxidation with variety of oxidizing agents.
The boiling points of aldehydes and ketones differ from hydrocarbons and ethers.
Aldehydes and ketones undergo nucleophilic addition reaction due to presence of electrophilic carbonyl carbon.
Nucleophile and a proton add across the carbon oxygen double bond.
Identify the product Y in the following reaction
\(\text{CH}_3\text{-CH = CH – CH}_2\text{OH}\) \(\xrightarrow{\text{Pyridinium Chlorochromate}}\) \(\rightarrow\text{Y}\)

Among the following reaction(s) which gives (give) tert-butylbenzene as the major product
(A)
(B)
(C)
(D)
(E)

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The main cause of basicity of oxoacids of phosphorous is :

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There are three kinds of amines which are primary, secondary and tertiary amines. These amines may have alkyl group or aryl group or both alkyl and aryl groups. These amines can be distinguished from one another by various chemical tests.
An amine A on treatment with benzene sulphonyl chloride gives a compound B which easily dissolves in an alkali : then A is :

Decreasing \(Pk_b\) value of following in solution :
(A) \(CH_3CH_2NH_2\)
(B) \((CH_3CH_2)_2NH\)
(C) \((CH_3CH_2)_3N\)
(D) Aniline (Structure shown)
(E) 4-Methoxyaniline (Structure shown)
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Second period elements of p-Block differs from the rest of their group members due to their small atomic size, high electronegativity, high ionization enthalpy and absence of d-orbitals. The elements from the second period like C, N, O have unique property of forming \(p \pi-p \pi\) multiple bonds whereas other heavier elements of p-block form \(d \pi-p \pi\) multiple bonds. This changes the properties of second period elements to great extent. Also the single bond strength of the p-block elements with their own atoms gets affected by their atomic size and presence of lone pairs.
Inert pair effect also affects the properties of the p-Block elements especially for those elements which are present from 4th period onward and this happens due to poor screening effect of inner (n-1)d subshell electrons.
\(\text{N}_2\) is a gas wherein \(\text{P}_4\) is a solid, because -

Match the items given in List-I with items given in List-II

List-I	List-II
(A) Interstitial Compounds	(I) Large number of complex
(B) Alloy formation	(II) Chemically inert
(C) Transition metals	(III) Ni
(D) Catalytic hydrogenation	(IV) Blend of different metals

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The base of transistor is:

A motor has an armature resistance \( 4 \, \Omega \). It is operating on 220 V. At its full speed, it develops a back emf of 200 V. The current in the armature when the motor is switched on will be :

Out of all isomers of \(\text{C}_4\text{H}_{11}\text{N}\), how many are primary amines?

(A) \(\frac{d}{d x} a^x=\frac{a^x}{\log _e a}\)
(B)\(\frac{d}{d x} e^{a x}=a e^{a x}\)
(C) \(\frac{d}{d x} x^x=x \cdot x^{x-1}\)
(D) \(\frac{d}{d x} x^a=a x^{a-1}\)
(E) \(\frac{d}{d x} a^a=0\)
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The capacitance of a capacitor becomes \(\frac{7}{6}\) times its original value if a dielectric slab of thickness \(t=\frac{2}{3} d\) is introduced between the plates, where \(d\) is the separation between the plates. The dielectric constant of the slab is: