Match the coordination compounds given in List-l with the central metal atoms given in List-ll

List-I (Coordination compound)	List-II (Central metal atom)
(A) blood pigment	(I) iron
(B) chlorophyll	(II) magnesium
(C) vitamin B12	(III) rhodium
(D) wilkinson catalyst	(IV) cobalt

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Elements of group-15, 16 and 17 form compounds with hydrogen with general formula MH3, \(H 2 M\) and HX (called hydrogen halides). Stability of these hydrides, along with M-H bond strength and basic nature decreases down the group. Boiling point of these hydrides mainly depends on the strength of their inter molecular forces.
Decreasing order of boiling point of group 15 hydrides is:
A. \(NH _3\)
B. \(PH _3\)
C. \(AsH _3\)
D. \(SbH _3\)
E. \(BiH _3\)
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The carbonyl group of aldehydes and ketones is highly polar. The positively charged carbon is readily attacked by electron-rich nucleophile and the negatively charged oxygen atom is attacked by an electro-deficient electrophile. Aldehydes and ketones undergo nucleophilic addition reactions in the presence of acid or a base. The mechanism involves attack of a nucleophile on the electron deficient carbonyl carbon to form a tetrahedral intermediate. A new bond is formed between the carbon and oxygen. Protonation of the anion furnished by the reaction medium yields a neutral addition product. The addition product is same whether the reaction is catalyzed by acid or a base. For example in the presence of base aldehydes and ketones react with hydrogen cyanide to form cyanohydrin.
The source of nucleophile in the base catalyzed cyanohydrin formation is:

The major product of Kolbe's reaction is used for the synthesis of a precursor substrate in the preparation of aspirin
The electrophile used in Kolbe's reaction is

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The osmotic pressure is one of the four colligative properties which depends on the number of particles of solute in the solution, irrespective of their nature. The osmotic pressure is equal to the product of concentration, gas constant and temperature. It is the most commonly used property for the determination of the molar mass of biomolecules. In many situations, the molecules get dissociated or associated when they are dissolved in a solvent, thereby changing the number of molecules in the solution. As a result, an abnormal molecular mass is obtained. The extent of dissociation or association is given by van't Hoff factor (i), which is the ratio of normal molar mass to abnormal molar mass. It is related with the degree of association or ionization. The introduction of van't Hoff factor in the osmotic pressure equation modifies the equation.
\[Itext\{Osmotic pressure\} ((Pi) \text\{of a solution does not depend upon\}\}]

2.0 g of benzoic acid dissolved in 25 g of benzene shows a depression in freezing point of 1.62 K. Molal depression constant \(K_f\) of benzene is \(4.9\text{ K kg mol}^{-1}\). What is the percentage association of the acid?

Answer the question on basis of passage given below :
Look at the following chemical reactions and answer the following question:
(A) \(C_7H_8 \xrightarrow{\text{Conc. HNO}_3, 0^\circ C}
(B) \xrightarrow{Sn/HCl}
(C) \xrightarrow{NaNO_2/H_3O^+}
(D) \xrightarrow{H_2O, Heat} (E)\)
(E) \(CH_3I \xrightarrow{KMnO_4/H^+}
(F) \xrightarrow{H_3O^+}
(G) \xrightarrow{NaOH} (H)\)
Which of the following compounds will form dimer ?

In the following sequence of reactions :
CH3–CH(NH2) - CH3 $\xrightarrow{HNO_2}$[A] $\xrightarrow{Oxidation}$[B] $\xrightarrow{H^{+}/H_{2}O}$ CH3MgBr
[C] The compound [C] is :

In an ac circuit, a coil of self-inductance L is connected in series with an electric bulb of resistance R. If the frequency of ac supply increases, then

Fertilization in human female takes place in -

The value of is \(\left|\begin{array}{cc}x^2-x+1 & x-1 \\ x+1 & x+1\end{array}\right|\) equal to

The endosperm is completely consumed by the developing embryo before seed maturation in :

For which values of \(a, f(x)=a(x+\sin x)\) is an increasing function?