CUET · CHEMISTRY · PYQ PAPER 2025
Match the complex species given in List-l with the possible isomerism given in List-ll:
| List-l Complex species | List-ll Isomerism |
| (A) \(\left[ Co \left( NH _3\right)_4 Cl _2\right]^{+}\) | (I) optical |
| (B) cis- \(\left[ Co ( en )_2 Cl _2\right]^{+}\) | (II) ionization |
| (C) \(\left[ Co \left( NH _3\right)_5\left( NO _2\right)\right] Cl _2\) | (III) coordination |
| (D) \(\left[ Co \left( NH _3\right)_6\right]\left[ Cr ( CN )_6\right]\) | (IV) geometrical |
- A (А)-(I), (B)-(Ⅱ), (C)-(IV), (D)-(III)
- B (А)-(I), (Β)-(II), (C)-(III), (D)-(IV)
- C (A)-(IV), (B)-(I), (С)-(III), (D)-(II)
- D (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
Answer & Solution
Correct Answer
(D) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
Step-by-step Solution
Detailed explanation
(A) \( \left[ Co \left( NH _3\right)_4 Cl _2\right]^{+}\) is \(MA_4B_2\) type, shows geometrical isomerism (cis/trans). (B) cis- \( \left[ Co ( en )_2 Cl _2\right]^{+}\) is \(cis-M(AA)_2B_2\) type, is chiral, shows optical isomerism. (C)…
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