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CUET · CHEMISTRY · PYQ PAPER 2025

Match the complex species given in List-l with the possible isomerism given in List-ll:
List-l Complex speciesList-ll Isomerism
(A) \(\left[ Co \left( NH _3\right)_4 Cl _2\right]^{+}\)(I) optical
(B) cis- \(\left[ Co ( en )_2 Cl _2\right]^{+}\)(II) ionization
(C) \(\left[ Co \left( NH _3\right)_5\left( NO _2\right)\right] Cl _2\)(III) coordination
(D) \(\left[ Co \left( NH _3\right)_6\right]\left[ Cr ( CN )_6\right]\)(IV) geometrical
Choose the correct answer from the options given below:

  1. A (А)-(I), (B)-(Ⅱ), (C)-(IV), (D)-(III)
  2. B (А)-(I), (Β)-(II), (C)-(III), (D)-(IV)
  3. C (A)-(IV), (B)-(I), (С)-(III), (D)-(II)
  4. D (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
Verified Solution

Answer & Solution

Correct Answer

(D) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)

Step-by-step Solution

Detailed explanation

(A) \( \left[ Co \left( NH _3\right)_4 Cl _2\right]^{+}\) is \(MA_4B_2\) type, shows geometrical isomerism (cis/trans). (B) cis- \( \left[ Co ( en )_2 Cl _2\right]^{+}\) is \(cis-M(AA)_2B_2\) type, is chiral, shows optical isomerism. (C)…
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