Match List-l with List-II

List-l (Compound/Elements)	List-II (Uses)
(A) Magnesium based alloy is constituent of	(I) Bullets
(B) Lanthanoid oxide	(II) Petroleum cracking
(C) Mixed oxides of Lanthanoids are employed in	(III) Television screen
(D) Misch metal	(IV) Lanthanoid metal and iron

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Van't Hoff factor (i) is given by

Select the correct statements from the following:
(A) Mn show the highest oxidation state in first transition series elements.
(B) Titanium (II) is more stable than titanium (III) and titanium (IV).
(C) Scandium does not exhibit variable oxidation states.
(D) Zn form complexes with only (II) oxidation state.
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Arrange the following compounds in increasing order of their acidic strength:
(A) 3-nitrophenol
(B) 3,5-Dinitrophenol
(C) 2,4,6 -Trinitrophenol
(D) Phenol
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Match List - I with List - II

List - I (Cell Type)	List - II (Characteristic/Reaction)
A. Fuel Cell	I. Rechargeable
B. Mercury Cell	II. Reaction at anode, \(\text{Zn} \rightarrow \text{Zn}^{2+} + 2\text{e}^{-}\)
C. Leclanche Cell	III. Cell reaction \(2\text{H}_2 + \text{O}_2 \rightarrow 2\text{H}_2\text{O}\)
D. Ni-Cd Cell	IV. Gives steady potential

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Magnetic moment of \(\text{Co}^{2+}\) will be

The standard electrode potential for a Daniell cell is 1.1 V. Calculate the standard Gibbs energy for the reactiction
\(Zn ( s )+ Cu ^{2+}( aq ) \rightarrow Zn ^{2Solution+}( aq )+ Cu ( s )\)

The resistance of a cylindrical conductor is :

\(\text{Ni}^{2+}\) in \([\text{NiCl}_2(\text{H}_2\text{O})_4]\) and \(\text{Fe}^{3+}\) in \([\text{Fe}(\text{CN})_6]^{3-}\) are called:

Single step large mutation leading to speciation is also called:

The combined resistance \(R\) of two resistors \(R_1\) and \(R_2\left(R_1, R_2>0\right)\) is given by\(\frac{1}{R}=\frac{1}{R_1}+\frac{1}{R_2}\) if \(R_1+R_2=C\) (a constant). The maximum resistance \(R\) is obtained when

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Carboxylic acids are the organic compounds which comprise of carboxyl functional group, -COOH. These are generally found in nature, some higher members are known as fatty acids as they occur in natural fats as esters of glycerol. They can be prepared from oxidation of alcohols and aldehydes, hydrolysis of nitriles and amides and Grignard reagents. They are stronger acids than simple phenols and alcohols. but weaker than mineral acids. Substituents affect the acidity of aliphatic and aromatic carboxylic acids. They undergo reactions involving cleavage of -OH and C-OH bond. Carboxylic acids having an alpha hydrogen get halogenated in the presence of red phosphorus to form alpha halo carboxylic acids. The reaction is known as Hell Volhard Zelinsky reaction. Besides these aromatic carboxylic acids undergo electrophilic substitution reactions. They are versatile and are employed in the manufacture of various useful compounds. For example, methanoic acid is used in rubber, textile, dyeing, leather and electroplating industries. Higher fatty acids are used in the manufacture of soaps and detergents. Esters of Benzoic acid are used in perfumery.
Benzoic acid in the presence of conc. \(HNO _3\) and conc. \(H _2 SO _4\) gives major product as:

For a particular reaction taking place at \(\text{T} = 300 \text{ K}\), \(\text{E}_a= 300 \text{ kJ/mol}\) and \(\text{log k} = -3.45\); calculate the temperature at which the rate constant becomes 4 times that of k. (Given \(\text{log } 2 = 0.3010\))