CUET · CHEMISTRY · PYQ PAPER 2023
Match List - I with List - II.
| List - I (Vitamins) | List - II (Disease) |
| (A) Vitamin-B1 | (I) Scurvy |
| (B) Vitamin-A | (II) Malaria |
| (C) Vitamin-C | (III) Xerophthalmia |
| (D) Vitamin-D | (IV) Beri Beri |
- A (A)-(II), (B)-(I), (C)-(III), (D)-(II)
- B (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
- C (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
- D (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
Answer & Solution
Correct Answer
(B) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
Step-by-step Solution
Detailed explanation
(A)-(IV), (B)-(III), (C)-(I), (D)-(II)
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There are some deposits of nitrates and phosphates in the earth’s crust. Nitrates are more soluble in water. Nitrates are difficult to reduce under laboratory conditions, but microbes do it easily. Ammonia forms a large number of complexes with transition metals. Hybridisation easily explains the ease of sigma donation capability of NH₃ and PH₃. Phosphine is an inflammable gas, prepared from white phosphorus.
Which of the following is the correct statement?
A. Between NH₃ and PH₃, NH₃ is a better electron donor because the lone pair of electrons occupy spherical 's' orbital and is less directional.
B. Between NH₃ and PH₃, NH₃ is a better electron donor because the lone pair of electrons occupies sp³ orbital and is more directional.
C. Between NH₃ & PH₃, PH₃ is a better electron donor because the lone pair of electrons occupies sp² orbital and is more directional.
D. Between NH₃ & PH₃, PH₃ is a better electron donor because the lone pair of electrons occupies 's' orbital and is less directional.
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When a metal is placed in a solution of its ions, the metal can lose electron and can go in the solution as ion or the metal ion in the solution can take electron from the electrode and get deposited as metal. Thus, the electrode acquires either positive or negative charge with respect to the solution leading to the development of a potential difference between the metal electrode and the solution. This potential difference is called the electrode potential of the metal. The electrode potential of a metal is a measure of relative tendency to undergo oxidation (loss of electron) or reduction (gain of electron). When the concentration of the ions in the solution is unity, the electrode potential is called standard electrode potential. The magni of potential depends upon the nature of electrode, concentration of ions in solution and the temperature. In a galvanic cell, the electrode at which oxidation occurs is known as anodic half-cell and the electrode at which reduction occurs is known as cathodic half cell. The emf of the cell in terms of standard reduction potential is given by \(E_{\text {cell }}^{\circ}=E_{\text {cathode }}^{\circ}-E_{\text {anode. }}^{\circ}\).The standard free energy change of the redox reaction taking place in the cell is related to \(E_{\text {cell }}^{\circ}\) by \(\Delta G^{\circ}=-n F E^{\circ}\). A redox reaction would occur spontaneously if the free energy change is negative. The equilibrium constant of the reaction is related to the standard free energy change by \(\Delta G^{\circ}=-R T \ln K\).
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