Match List-I with List-II

List-I (Reaction)	List-II (Name)
(A) \({CH}_3 {CHO}+{Dil} {NaOH} \longrightarrow {CH}_3 {CHOHCH}_2 {CHO}\)	(I) Aldol Reaction
(B) \({CH}_3 {CH}_3 {CH}_2 {COOH}+{Br}_2 \xrightarrow[\text { (ii) } {H}_2 {O}]{\text { (i)Red P }} {CH}_2 {CH}_2 {CHBrCOOH}\)	(II) Cannizzaro Reaction
(C) \({C}_6 {H}_5 {CHO}+\) Conc. \({KOH} \longrightarrow {C}_6 {H}_5 {COONa}+{C}_6 {H}_5 {CH}_2 {OH}\)	(III) Haloform Reaction
(D) \({CH}_3 {COCH}_3 \xrightarrow{{NaOCl}} {CH}_3 {COONa}+{CHCl}_3\)	(IV) Hell Volhard Zelinski Reaction

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Read the passage carefully and answer:
Organic compounds derived from NH3 by replacing one or more H-atoms with alkyl or aryl groups will form primary, secondary and tertiary amines. The common methods which include their preparations are reduction of nitro group, amide group and nitrile group, Gabriel phthalimide synthesis and ammonolysis of alkyl halides. Amines are basic in nature due to the presence of a lone pair of electrons on the nitrogen atom. Important chemical properties of amines include acylation, alkylation and their interaction with nitrous acid. There are various tests which can distinguish different types of amines from each other, for e.g. carbylamine test, Hinsberg's test, coupling reaction etc. Another important class of compounds which can be derived from primary amines is azo compounds. These compounds are intensely colored and widely used as dyes in textile, leather and food industries.
How many different structural isomers that correspond to the molecular formula \(\mathrm{C}_3 \mathrm{H}_9 \mathrm{~N}\) are possible? Out of these, how many will give a positive carbylamine test?

Which type of amine produces \(\ N_2\) when treated with HONO?

Four different electrolyte solutions with the concentrations given below have the same molar conductivity value of \(1.29 \times 10^{-4} \mathrm{~S} \mathrm{~m}^2 \mathrm{~mol}^{-1}\). Arrange them in increasing order of their conductivity values:
(A) 0.1 M
(B) 0.075 M
(C) 0.15 M
(D) 0.05 M
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Which of the following electrolytes will have maximum coagulating value for \(\text{AgI/Ag}^{+}\) sol?

The quantity of charge required to obtain \(2\text{ mol}\) of \(\text{Mn}^{2+}\) from \(\text{MnO}_4^{-}\) is:

The \(C-O-H\) bond angle of alcohol is:

hen a mixture of \(K _2 Cr _2 O _7\) and NaCl is warmed with concentrated \(H _2 SO _4\), red vapours of \((A)\) are evolved, which turn NaOH yellowish due to formation of compound (B). A and B respectively are:

Match List-I (Name) with List-II (Structure)

List-I (Name)	List-II (Structure)
(A) Cinnamaldehyde	(I)
(B) Vanillin	(II)
(C) Salicylaldehyde	(III)
(D) Benzophenone	(IV)

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An alpha particle is moving in a magnetic field \( (3\hat{i} + 2\hat{j}) \text{ T} \) with the velocity \( (7 \times 10^5 \hat{i}) \text{ m/s} \). The magnetic force acting on the particle is:

A wire of resistance \( 5\Omega \) is drawn out so that its length is increased by thrice its original length. The new resistance would be :

DNA recombinant technology involves the use of restriction endonucleases. After having cloned the gene of interest and having optimised the conditions to induce the expression of the target protein, one has to consider producing it on a large scale. The cells harbouring cloned genes of interest may be grown on a small scale in the laboratory. In order to link the alien DNA, the vector needs to have very few, preferably single, recognition sites for the commonly used restriction enzymes. Presence of more than one recognition sites within the vector will generate several fragments, which will complicate the gene cloning. In Biolistics or gene gun method cells are bombarded with high velocity micro particles of gold or tungsten coated with DNA. The ligation of alien DNA is carried out at a restriction site present in one of the two antibiotic resistance genes. For example, you can ligate a foreign DNA at the BamH I site of tetracycline resistance gene in the vector pBR322. Since the DNA is enclosed within the membranes, we have to break the cell open to release DNA along with other macromolecules such as RNA, proteins, polysaccharides and also lipids. The RNA can be removed by treatment with ribonuclease whereas proteins can be removed by treatment with protease. Other molecules can be removed by appropriate treatments and purified DNA ultimately precipitates out after the addition of chilled ethanol.
Which one of the following enzymes should be used to break the bacterial cells for isolation of DNA?

Match List-I with List-II

List-I Scientists	List-II Discoveries
(A) Walter Sutton and Boveri	(I) Linkage and recombination of genes on a chromosome
(B) Gregor Mendel	(II) Chromosomal theory of inheritance
(C) Thomas Hunt Morgan	(III) Law of inheritance
(D) Alfred Sturtevant	(IV) Genetic map

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