Match List - I with List - II

List - I	List - II
(A) \([Ni(CN)_4]^{2-}\)	(I) \(EDTA^{4-}\)
(B) bidentate	(II) paramagnetic
(C) chelate ligand	(III) diamagnetic
(D) \([Ni(Cl)_4]^{2-}\)	(IV) oxalate

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The number of reacting species (atoms, ions or molecules) taking part in an elementary reaction, which must collide simultaneously in order to bring about a chemical reaction is called molecularity of a reaction. In the rate equation Rate \(=k[\mathrm{~A}]^x[\mathrm{~B}]^y\)
\(x\) and \(y\) indicate how sensitive the rate is to the change in concentration of A and B, respectively. Sum of these exponents, i.e., \(x +y\) gives the overall order of a reaction where \(x\) and \(y\) represent the order with respect to the reactants A and B respectively. Hence, the sum of powers of the concentration of the reactants in the rate law expression is called the order of that chemical reaction. For a first order reaction, the concentration of the reactant varies as \([\mathrm{R}]=[\mathrm{R}]_0 e^{-k t}\)
The units of first and zero order rate constant of reactions are respectively:

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The term vitamin was coined from the word vital +amine since the earlier identified compounds had amino groups. Later work showed that most of them didn't contain amino groups. They are very essential for the body. They has to be taken various diet or in the form of medicines also.
Vitamins are classified into two groups depending upon their solubility in water or fat.
Fat soluble vitamins are soluble in fat and oils but insoluble in water. They are stored in liver and adipose (fat storing) tissues Water soluble vitamins are soluble in water. These must be supplied regularly in diet because they are readily excreted in urine and cannot be stored in our body.
Deficiency of which vitamin causes Rickets?

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The resistance (\(R\) ) of an object is given by the expression \(R=\rho \frac{l}{A}\).
The inverse of \(R\) is called conductance and the inverse of \(\rho\) is called conductivity or specific conductance represented by \(\kappa\).
The conductivity depends upon the nature of the material (insulator, semiconductor or conductor) and the temperature of the substance.
Similarly, the conductance due to the ions present in the solution (ionic conductance) depends upon the nature of the electrolyte, size of ions, the nature of the solvent and the temperature.
Molar conductivity ( \(\Lambda_m\) ) of a solution at a given concentration is the conductance of volume \(V\) containing one mole of electrolyte kept between two electrodes of area \(A\) and unit distance apart.
It is given by the expression \(\Lambda_m=\kappa V\).
Molar conductivity increases with decrease in concentration and when concentration approaches zero, it is called limiting molar conductivity.
The decrease is linear for a strong electrolyte. However, for a weak electrolyte the change is gradual at higher concentrations and sharp near zero concentration.
Using limiting molar conductivity values of strong electrolytes we can calculate the limiting molar conductivity of weak electrolytes using Kohlrausch law of independent migration of ions.
From molar conductivity and limiting molar conductivity we can determine the degree of dissociation \(\left(\frac{\Lambda_m}{\Lambda_m^0}\right)\) and the ionization constant of a weak acid.
SI units of conductance and conductivity, respectively, are ___________

The type of isomerism exhibited by the complex \([\text{CoCl}_2 (\text{en})_2]\) is:

Answer the question on the basis of passage given below:
Second period elements of p-Block differs from the rest of their group members due to their small atomic size, high electronegativity, high ionization enthalpy and absence of d-orbitals. The elements from the second period like C, N, O have unique property of forming \(p \pi-p \pi\) multiple bonds whereas other heavier elements of p-block form \(d \pi-p \pi\) multiple bonds. This changes the properties of second period elements to great extent. Also the single bond strength of the p-block elements with their own atoms gets affected by their atomic size and presence of lone pairs.
Inert pair effect also affects the properties of the p-Block elements especially for those elements which are present from 4th period onward and this happens due to poor screening effect of inner (n-1)d subshell electrons.
Catenation tendency of Nitrogen is weaker than Phosphorus, because

Question 4 (IUPAC Name of Freon 12):
The correct IUPAC name of Freon 12 is

In the given circuit, \( R_1 = 6 \Omega \), \( R_2 = 3 \Omega \), \( C_1 = 4 \mu F \) and \( C_2 = 5 \mu F \). When key K is closed, the charge stored in \( C_1 \) is

A battery has an e.m.f 12 V and internal resistance 2 \(\Omega\) This battery is connected to a variable resistor 0 to 5 \(\Omega\). The value of current for which the rate of heat production in the resistor is maximum:

The transfer of integral number of ___________ is one of the evidence of quantization of electric charge.

If a line makes angles \(\alpha, \beta, \gamma\) with the positive directions of \(x\)-axis, \(y\)-axis and \(z\)-axis respectively, then \(\sin ^2 \alpha+\sin ^2 \beta+\sin ^2 \gamma\) is equal to:

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The carbonyl group of aldehydes and ketones is highly polar. The positively charged carbon is readily attacked by electron-rich nucleophile and the negatively charged oxygen atom is attacked by an electro-deficient electrophile. Aldehydes and ketones undergo nucleophilic addition reactions in the presence of acid or a base. The mechanism involves attack of a nucleophile on the electron deficient carbonyl carbon to form a tetrahedral intermediate. A new bond is formed between the carbon and oxygen. Protonation of the anion furnished by the reaction medium yields a neutral addition product. The addition product is same whether the reaction is catalyzed by acid or a base. For example in the presence of base aldehydes and ketones react with hydrogen cyanide to form cyanohydrin.
The source of nucleophile in the base catalyzed cyanohydrin formation is:

In the depletion region of an unbiased p-n junction diode there are