Match List I with List II

LIST I	LIST II
A. Gatterman-Koch reaction	I. Diphenyl
B. Stephens reaction	II. Ethyl amine
C. Hoffmann Bromamide degradation	III. Benzaldehyde
D. Fittig reaction	IV. Acetaldehyde

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Which of the following will not respond to Fehling's Test?
(A) Benzaldehyde
(B) Acetone
(C) Acetaldehyde
(D) Acetophenone
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Which of the following statement(s) is correct?
(A). Keratin is an example of fibrous protein.
(B). Fibrous proteins are water-soluble, while globular proteins are water-insoluble.
(C). Polypeptide chains in fibrous proteins run parallel and are held together by hydrogen and disulphide bonds.
(D). Insulin and albumins are common examples of globular proteins.
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Carbonyl compounds such as aldehydes, ketones, and carboxylic acids play an important role in the biochemical process of plants and animal kingdom.
Many aldehydes and ketones find applications in dye, perfumery and other industries.
The carbonyl carbon stom is \(s p^2\)-hybridized forming three sigma and one pi-bond with oxygen.
C-O bonds are polar bond due to high electronegativity of oxygen than carbon.
Hence the carbonyl carbon behaves as an electrophilic center and oxygen as a nucleophilic centre.
Primary and secondary alcohols yield aldehydes and ketones respectively upon oxidation with variety of oxidizing agents.
The boiling points of aldehydes and ketones differ from hydrocarbons and ethers.
Aldehydes and ketones undergo nucleophilic addition reaction due to presence of electrophilic carbonyl carbon.
Nucleophile and a proton add across the carbon oxygen double bond.
The starting compound Y in the following reaction is
\(\text{Y}\) \(\xrightarrow{\text{oxidation}}\) \(\text{aldehyde}\) \(\xrightarrow{\text{oxidation}}\) \(\text{carboxylic acids}\)

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Amines are classified as primary \(\left(1^{\circ}\right)\), secondary \(\left(2^{\circ}\right)\) and tertiary \(\left(3^{\circ}\right)\) depending upon the number of hydrogen atoms replaced by alkyl or aryl groups in ammonia molecules. Aliphatic amines are a stronger bases due to \(+I\) effect of an alkyl groups. Intermolecular hydrogen bonding in primary and secondary amines affects the boiling points of amines. The intermolecular association is more in primary amines than in secondary amines as there are more number of hydrogen atoms available for hydrogen bond formation. Nitro compounds are reduced to amines by passing hydrogen gas in the presence of finely divided nickel, palladium or platinum and also by reduction with metals in an acidic medium. Gabriel synthesis is used for the preparation of primary amines. Primary amines react with nitrous acid to give unstable diazonium-salts which can be used to synthesize a variety of compounds.
The reaction is an example of

Which of the following will be having maximum magnetic moment?
\(( Fe =26, Mn =25, Co =27)\)

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Carboxylic acids are the organic compounds which comprise of carboxyl functional group, -COOH. These are generally found in nature, some higher members are known as fatty acids as they occur in natural fats as esters of glycerol. They can be prepared from oxidation of alcohols and aldehydes, hydrolysis of nitriles and amides and Grignard reagents. They are stronger acids than simple phenols and alcohols. but weaker than mineral acids. Substituents affect the acidity of aliphatic and aromatic carboxylic acids. They undergo reactions involving cleavage of -OH and C-OH bond. Carboxylic acids having an alpha hydrogen get halogenated in the presence of red phosphorus to form alpha halo carboxylic acids. The reaction is known as Hell Volhard Zelinsky reaction. Besides these aromatic carboxylic acids undergo electrophilic substitution reactions. They are versatile and are employed in the manufacture of various useful compounds. For example, methanoic acid is used in rubber, textile, dyeing, leather and electroplating industries. Higher fatty acids are used in the manufacture of soaps and detergents. Esters of Benzoic acid are used in perfumery.
Identify the strongest acid

In an electromagnetic wave, if \(\vec{B}\) and \(\vec{E}\) represent the magnetic field and electric field respectively, then the direction of propagation of the electromagnetic wave is along the direction of:

The function \(f(x)=x+\frac{1}{x}\) has

Which of the following are true for optical instruments?
(A) A simple microscope is a converging lens of large focal length.
(B) A telescope is used to provide angular magnification of distant objects.
(C) The objective lens of a telescope has a smaller focal length than the eyepiece.
(D) The magnifying power of a telescope is the ratio of the focal length of the objective lens
to the focal length of the
eyepiece.
(E) A simple microscope is a converging lens of small focal length
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\(\int \frac{x}{(x-1)(x-2)} d x\) is equal to (where C is a constant of integration)

Identify the correct statements for Ethylene dichloride and Ethylidene chloride
(A) They represent structural isomers.
(B) Both are formed by reaction of ethene with chlorine in presence of\(CCl _4\)
(C) Both the compounds belong to a class of dihalocompounds
(D) Both the compounds are optically inactive.
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The gene encoding resistance to which antibiotic are considered useful selectable marker for E. coli.
(A) ampicillin
(B) tetracycline
(C) kanamycin
(D) penicillin
(E) chloramphenicol
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