Match List - I with List - II.

List – I	List – II
(A) Glycosidic linkage	(I) Monomeric units of nucleic acid
(B) Peptide linkage	(II) Sugar-heterocyclic base combination
(C) Nucleotide	(III) Linkage between two amino acid units
(D) Nucleoside	(IV) Linkage between two mono saccharide units

Choose the correct answer from the options given below :

The rate constant for a reaction is \(3.5 \mathrm{~mol}^{-1} \mathrm{~L} \mathrm{~s}-^{-1}\). The order of the reaction is:

Antipyretic drugs prevent platelet coagulation, apart from reducing fever. Because of this action, antipyretic aspirin is also used:

When aniline is reacted with benzoyl chloride, the correct product is

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Alcohols are versatile compounds as they can act as both nucleophile and electrophile. They undergo reactions based on cleavage of \(\mathrm{O}-\mathrm{H}\) and \(\mathrm{C}-\mathrm{O}\) bonds. The cleavage of \(\mathrm{O}-\mathrm{H}\) bond reflects the acidic character of alcohols. However they are weaker acids than water, phenol and carboxylic acids. Alkoxide ion formed by loss of proton from the OH group of alcohols reacts with water to form the corresponding conjugate acid - base pair. They act as Bronsted base due to presence of unshared electron pairs on oxygen.Both alcohols and phenol react with carboxylic acids, acid chlorides and anhydrides to form esters. The introduction of acetyl group in alcohols or phenol is known as acetylation. Alcohols react with hydrogen halides to form alkyl halides which form the basis of Lucas test. They also undergo acid catalyzed dehydration to form alkenes. Alcohols can be easily oxidized with variety of oxidizing agents. The nature of the product depends on the type of oxidizing agent and the nature of alcohol.
Lucas reagent is

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Amines are considered to be derivatives of ammonia obtained by replacement of hydrogen atoms with alkyl or aryl groups. They are usually prepared from nitro compounds, halides, amides, imides etc. The presence of hydrogen bonding influences its physical properties. In alkylamines, a combination of electron releasing steric and hydrogen bonding factors influences the stability of substituted ammonium cations in protic polar solvents and thus affects the basic nature of amines. Alkyl amines are found to be stronger bases than ammonia which is more basic than water. Primary and secondary amines are engaged in intermolecular association due to hydrogen bonding. This intermolecular association is more in primary amines than in secondary amines. Tertiary amines do not have intermoleulcar association due to the absenceof hydrogen atom available for hydrogen bonding. Thus, the boiling point of amines depends on hydrogen bonding. In aromatic amines, electron releasing and withdrawing groups increase and decrease their basic character. Aryl diazonium salts usually obtained from arylamine undergo replacement of the diazonium group with a variety of nucleophile. Their coupling reaction of aryl diazonium salts with phenol or arylamine results in formation of dyes.
The most basic species in the following is

Cr is reducing but Mn is oxidising in nature although both have \(\text{d}^1\) configuration. It is due to the reason that Cr configuration changes from

A solenoid with an iron core and a bulb are connected to an a.c. source. The bulb is glowing with certain brightness. When the iron core is removed from the solenoid, the brightness of the bulb

Evaluate the determinant \(\begin{vmatrix} x-y & y-z & z-x \\ y-z & z-x & x-y \\ z-x & x-y & y-z \end{vmatrix}\)

Grignard reagent should be prepared under anhydrous condition because

A cylindrical wire is stretched to increase its length by 10%. The percentage increase in resistance will be

The value of the integral \(\int e^x\left(\frac{1}{x}-\frac{1}{x^2}\right) d x\) is:

If \(y=\sin ^{-1} x\), then \(\left(1-x^2\right) \frac{d^2 y}{d x^2}\) is equal to