List-I (Name reaction.)	List-II (Reaction)
(A) Williamson ether synthesis	(I)
(B) Hydroboration oxidation	(II)
(C) Reimer-Tiemann reaction	(III)
(D) Friedel Craft Acylation reaction	(IV)

Choose the correct answer from the options given below:

Match List I with List II

List-l	List-II
A. \(K _2 SO _4( aq )\) with \(60 \%\) dissociation	I. \(i = 3 . 7\)
B. \(K _3\left[ Fe ( CN )_6\right]( aq )\) with \(90 \%\) dissociation	II. \(i=1.8\)
C. \(AlCl _3( aq )\) with \(80 \%\) dissociation	III. \(i=2.2\)
D. \(K _2 HgI _4( aq )\) with \(40 \%\) dissociation	IV. \(i=3.4\)

Choose the correct answer from the options given below :

The correct statement (s) for cubic close packed (ccp) three dimensional structure are :
(A) The number of the neighbours of an atom present in the top most layer is 12.
(B) The efficiency of atom packing is \(74\%\).
(C) The number of octahedral and tetrahedral voids per atom are 1 & 2, respectively.
(D) The unit cell edge length is \(2\sqrt{2}\) times the radius of the atom.
(E) The metals like Be, Cd, Mg, Zn have cubic close packed (ccp) structure.
Choose the correct answer from the options given below :

Werner was the first to describe the bonding features in coordination compounds. But his theory could not answer basic questions like :
(i) Why only certain elements possess the remarkable property of forming coordination compounds ?
(ii) Why the bonds in coordination compounds have directional properties ?
(iii) Why coordination compounds have characteristics magnetic and optical properties ?
Many approaches have been put forth to explain the nature of bonding in coordination compounds viz. Valence Bond Theory (VBT), Crystal Field Theory (CFT), Ligand Field Theory (LFT) and Molecular Orbital Theory (MOT).
We shall focus our attention on elementary treatment of the application of VBT and CFT to coordination compounds.
According to this theory, the metal atom or ion under the influence of ligands can use its ( \(n -1\) )d, ns np or ns, np, nd orbitals for hybridisation to yield a set of equivalent orbitals of definite geometry such as octahedral, tetrahedral, square planar and so on.
These hybridised orbitals are allowed to overlap with ligand orbitals that can donate electron pairs for bonding.
The formula which correctly represents Potassium tetra hydroxo zincate (II) is :

A radioactive substance decays with a rate constant of 9.2 x 10^-3 min^-1 Time taken for \(75 \%\) of the sample to decompose is

When benzene diazonium chloride reacts with phenol, it results in the formation of an orange colored compound (X); and when benzene diazonium chloride reacts with aniline, it results in the formation of a yellow colored compound ( Y ).
What are \(X\) and \(Y\) ?

The reaction shown above is known as

Self Inductance of coil causes :

Let R be the feasible region for a Linear Programming Problem and let \(z=a x+b y\) be the objective function. If R is bounded, then the objective function z has :

The area bounded by the curve \(y =\sin x\) between \(x =0\) and \(x =2 \pi\) is

Read the given paragraph carefully and answer the following questions:
Since the DNA is enclosed within the membranes, we have to break the cell open to release DNA along with other macromolecules such as RNA, proteins, polysaccharides and also lipids. This can be achieved by treating the bacterial cells/plant or animal tissue with enzymes such as lysozyme (bacteria), cellulase (plant cells), chitinase (fungus). There are some basic steps in genetically modifying an organism (i) identification of DNA with desirable genes; (ii) introduction of the identified DNA into the host; (iii) maintenance of introduced DNA in the host and transfer of the DNA to its progeny. Agrobacterium tumifaciens, a pathogen of several dicot plants is able to deliver a piece of DNA known as 'T-DNA' to transform normal plant cells into a tumor and direct these tumor cells to produce the chemicals required by the pathogen. Other molecules can be removed by appropriate treatments and purified DNA ultimately precipitates out after the addition of chilled ethanol. Selection of recombinants due to inactivation of antibiotics is a cumbersome procedure because it requires simultaneous plating on two plates having different antibiotics. Therefore, alternative selectable markers have been developed which differentiate recombinants from non-recombinants on the basis of their ability to produce colour in the presence of a chromogenic substrate. In this, a recombinant DNA is inserted within the coding sequence of an enzyme, ß'-galactosidase. This results into inactivation of the gene for synthesis of this enzyme, which is referred to as insertional inactivation.
Agrobacterium tumefaciens, a pathogen of several dicot plants, is able to deliver a piece of DNA known as:

The compound which oxidizes slowly in the presence of air to give extremely poisonous phosgene gas is

An \( \alpha \) particle and a proton enters a region of uniform magnetic field B with same momentum at right angle to magnetic field. The ratio of the radii of the circular paths of \( \alpha \) particle to proton is: