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CUET · CHEMISTRY · PYQ PAPER 2023

In case of phosphorus, \(\text{PCl}_3\) and \(\text{PCl}_5\) are possible while nitrogen only forms \(\text{NCl}_3\), and not \(\text{NCl}_5\). This due to :

  1. A Nitrogen is a gas while phosphorus is a solid at room temperature.
  2. B Nitrogen does not have vacant d-orbitals in its atom while phosphorus has vacant d-orbitals.
  3. C The electronegativity of nitrogen is higher than that of phosphorus.
  4. D The atom of nitrogen is smaller in size than phosphorus.
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Answer & Solution

Correct Answer

(B) Nitrogen does not have vacant d-orbitals in its atom while phosphorus has vacant d-orbitals.

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Detailed explanation

Nitrogen does not have vacant d-orbitals in its atom while phosphorus has vacant d-orbitals.
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