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CUET · CHEMISTRY · PYQ PAPER 2023

In aldehydes, the carbonyl group is bonded to a carbon and hydrogen, while in ketones it is bonded to two carbon atoms. The carbonyl compounds in which carbonyl group is bonded to oxygen are known as carboxylic acid and their derivatives.
Which series represents compounds in increasing order of acidity?

  1. A \(NO _2 CH _2 COOH > CF _3 COOH > ClCH _2 COOH > CH _3 COOH\)
  2. B \(NO _2 CH _2 COOH > ClCH _2 COOH > CF _3 COOH > CH _3 COOH\)
  3. C \(CH _3 COOH > CF _3 COOH > NO _2 CH _2 COOH > ClCH _2 COOH\)
  4. D \(CF _3 COOH > NO _2 CH _2 COOH > ClCH _2 COOH > CH _3 COOH\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(NO _2 CH _2 COOH > ClCH _2 COOH > CF _3 COOH > CH _3 COOH\)

Step-by-step Solution

Detailed explanation

Order of electron-withdrawing group (EWG) strength: \(CF_3 > NO_2 > Cl > CH_3\) (electron-donating group). Stronger EWG leads to higher acidity. Therefore, the decreasing order of acidity is: \(CF _3 COOH > NO _2 CH _2 COOH > ClCH _2 COOH > CH _3 COOH\).