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CUET · CHEMISTRY · PYQ PAPER 2025

If the molar conductivities at infinite dilution for \(\mathrm{CH}_3 \mathrm{COOK}, \mathrm{K}_2 \mathrm{SO}_4\) and \(\mathrm{H}_2 \mathrm{SO}_4\) are respectively, \(\mathrm{z}, \mathrm{y}\) and \(\times\left(\mathrm{S} \mathrm{cm}^2 \mathrm{~mol}^{-1}\right)\), the molar conductivity of \(\mathrm{CH}_3 \mathrm{COOH}\) at infinite dilution will be:

  1. A \((x-y+2 z) / 2\)
  2. B \((x-2 y+2 z) / 2\)
  3. C \((x-y-z)\)
  4. D \((2 x+y+2 z)\)
Verified Solution

Answer & Solution

Correct Answer

(A) \((x-y+2 z) / 2\)

Step-by-step Solution

Detailed explanation

\( \Lambda^0_{m}(\mathrm{CH}_3 \mathrm{COOH}) = \Lambda^0_{m}(\mathrm{CH}_3 \mathrm{COOK}) + \frac{1}{2}\Lambda^0_{m}(\mathrm{H}_2 \mathrm{SO}_4) - \frac{1}{2}\Lambda^0_{m}(\mathrm{K}_2 \mathrm{SO}_4) \) \( = z + \frac{1}{2}x - \frac{1}{2}y \) \( = \frac{2z + x - y}{2} \)…
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