Geometry of \(\left[ Ni ( CN )_4\right]^{2-}\) and \(\left[ NiCl _4\right]^{2-}\) are:

Match the coordination compounds given in List-l with the central metal atoms given in List-ll

List-I (Coordination compound)	List-II (Central metal atom)
(A) blood pigment	(I) iron
(B) chlorophyll	(II) magnesium
(C) vitamin B12	(III) rhodium
(D) wilkinson catalyst	(IV) cobalt

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Which of the following statement(s) is/are correct with reference to electrophilic aromatic substitution of \(\text{C}_6\text{H}_5\text{Cl}\)?
(A) Cl acts as an activating and o/p directing group
(B) Cl acts as a deactivating and o/p directing group
(C) acts as an activating and m directing group
(D) Cl acts as a deactivating and m directing group
(E) Presence of \(\text{NO}_2\) at p-position facilitates the reactions
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Which of following reagents will furnish ambident nucleophile?
(A) AgCN
(B) KCN
(C) AgNO2
(D) KNO2
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Arrange the following in increasing order of their molarity when their equal weights are dissolved in 250 mL of water.
(A) glucose \(\left(180 g mol ^{-1}\right)\)
(B) sodium carbonate (106 g mol-1)
(C) sodium hydroxide \(\left(40 g mol ^{-1}\right)\)
(D) acetic acid \(\left(60 g mol ^{-1}\right)\)
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Read the passage carefully and answer the following questions
There are mainly four series of the transition metals, \(3 d\) series ( \(S c\) to Zn), \(4 d\) series (Y to Cd), 5d series (La and Hf to Hg) and 6d series which has \(A c\) and elements from Rf to Cn. The two series of the inner transition metals; \(4 f\) (Ce to Lu) and \(5 f\) (Th to Lr) are known as lanthanoids and actinoids respectively. Their chemical properties are transitional between those of \(s\) and p-block elements. The transition metals (with the exception of Zn, Cd and Hg) are very hard and have low volatility. Their melting and boiling points are high. Transition metals have incomplete d subshell either in neutral atom or in their ions. With partly filled d orbitals these elements exhibit certain characteristic properties such as display of a variety of oxidation states, formation of coloured ions and entering into complex formation with a variety of ligands. The transition metals and their compounds are known for their catalytic activity.
In series Sc to Zn, the lowest enthalpy of atomization is shown by

A solution of 2.5 g of ethanoic acid in 75 g of benzene is prepared. What is the molar mass of ethanoic acid, moles of ethanoic acid, mass of benzene and molality of ethanoic acid?
(A) \(0.556 \text{ mol } kg^{-1}\)
(B) \(0.0417 \text{ mol}\)
(C) \(60 \text{ g } mol^{-1}\)
(D) \(0.075 \text{ kg}\)
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The iodoform test is used for the detection of

Study the following figure and answer the questions:

AUG codes for which amino acid?

The big holes in Swiss cheese are due to:
(A) Production of large amount of \(O _2\)
(B) Production of large amount of \(CO _2\)
(C) Production of large amount of \(H _2\)
(D) Bacterium Propionibacterium sharmanii
(E) Lactobacillus casei
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What will happen during the electrolysis of aqueous solution of \(CuSO_4\) by using platinum electrodes?
A. Copper will deposit at cathode.
B. Copper will deposit at anode.
C. Oxygen will be released at anode.
D. Copper will dissolve at anode.
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Question based on the following passage :
P-Block elements are placed in group 13 to 18 in the periodic table. Group 15 is nitrogen family.
Nitrogen can react with hydrogen, oxygen, halogens etc. It shows multiple oxidation states in its various oxides i.e. \(N_2O, N_2O_3, N_2O_5\) etc. Important allotropic forms of phosphorus are white, red and black phosporus. Various compounds of phosphorus are phosphine, \(PCl_3, PCl_5\) and oxoacids of phosphorus. Oxidation states \(+1\) to \(+5\) are seen in various oxoacids of phosphorus. Group 17 elements are collectively known as halogens. Bond dissociation enthalpy of \(F_2\) is smaller than \(Cl_2\).
The gases present in group 18 are chemically unreactive, they form only few compounds. Neil Bartlett (in 1962) observed the reaction of a noble gas. Since then, many noble gas compounds have been synthesised.
Following statements are given regarding structure of \(N_2O_5\) :
(A) It has an angular structure
(B) It has a planar structure
(C) There are 6 sigma and 2 pi bonds
(D) There are 5 sigma and 2 pi bonds
(E) There are 6 sigma and 3 pi bonds
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A swimmer whose speed in still water is \(6 km / hr\), swims between two points in a river and returns to the starting point. He took 20 minutes more to cover the distance upstream than downstream. If the speed of the stream is \(3 km / hr\), then the distance between the two points is: