Choose the correct statement/statements:
(A) Denaturation of protein causes loss of secondary and tertiary structure
(B) Nucleotides are joined together by diester linkage
(C) DNA contains Adenine, Guanine, cytosine and Uracil
(D) Amino acids show amphoteric behaviour
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Match List-l with List-II

List-I	List-II
(A) Kolbe's reaction	(I) Preparation of symmetrical and unsymmetrical ethers
(B) Williamson synthesis	(II) Preparation of Salicylic acid
(C) Lucas test	(III) Organo-Magnesium halide
(D) Grignard's reagent	(IV) Distinction between different types of alcohols

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Read the passage carefully and answer the Questions
Carboxylic acids are the earliest organic compounds isolated from nature. These are also known as organic acids but are weaker acids as compared to mineral acids. However, they are more acidic than alcohols and phenols because of greater resonance stabilization of the parent acid and its conjugate base. The acidic strength is determined by the \(K _a\), which is called the acidity constant. The greater the value of \(K _a\), the greater the tendency of the acid to ionize and hence the stronger the acid. The acidic strength of the saturated aliphatic carboxylic acid depends upon the inductive effect and its position with respect to - COOH groups. Electron-donating substituents tend to decrease whereas electron-withdrawing substituents tend to increase the acidic strength. The acidic strength of the aromatic carboxylic acid, on the other hand depends upon both the inductive effect and the resonance effect of the substituents.
\(p K_a\) of chloroacetic acid is lower than acetic acid because of

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Aldehydes are generally more reactive than ketones in nucleophilic addition reactions due to steric and electronic reasons. Sterically, the presence of two relatively large substituents in ketones hinders the approach of nucleophile to carbonyl carbon more than aldehydes having only one such substituent Electronically aldehydes are more reactive than ketones because two alkyl groups reduce the elctrophilicity of the carbonyl more effectively than in former.
4-Hydroxy-4-methylpentan-2-one and 4-methylpent-3-en-2-one are the products obtained from A by aldol
condensation. \(A\) is:

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The degeneracy of the \(d\) orbitals has been removed due to ligand electron-metal electron repulsions in the octahedral complex to yield three orbitals of lower energy, \(t_{2 g}\) set and two orbitals of higher energy, \(e_g\) set. This splitting of the degenerate levels due to the presence of ligands in a definite geometry is termed as crystal field splitting and the energy separation is denoted by \(\Delta_0\). Thus energy of the two \(e_g\) orbitals will increase by \((3 / 5) \Delta_{\circ}\) and that of three \(t_{2 g}\) will decrease by \((2 / 5) \Delta_0\). The crystal field splitting \(\Delta_{ o }\) depends upon the field produced by the ligand and charge on the metal ion. Some ligands are able to produce strong fields, in which case the splitting will be large, whereas others produce weak fields and consequently result in small splitting of \(d\) orbitals. Relative magnitude of crystal field splitting energy \(\Delta_{\circ}\) and pairing energy, \(P\) (energy required for electron pairing in a single orbital) determine the formation of low spin ( \(\Delta_0>P\) ) or high spin ( \(\Delta_0<P\) ) complex. In tetrahedral coordination entity formation, the \(d\)-orbital splitting is inverted and is smaller as compared to the octahedral field splitting. The crystal field theory attributes the colour of the complex to \(d-d\) transition of the electron. The colour of the coordination compounds depends on the crystal field splitting. In the absence of ligand, crystal field splitting does not occur and hence the substance is colourless.
Choose the correct order of the ligands in their increasing crystal field splitting:

Out of the following given statements, the incorrect statements are;
(A) 2, 2, 6-Trimethylcyclohexanone forms a cyanohydrin in good yield, but the cyclohexanone doesn't.
(B) There are two amino groups in semicarbazide and both can be involved in the formation of semicarbazones.
(C) Mononitration of benzaldehyde will form m-nitrobenzaldehyde.
(D) Mononitration of acetophenone will form m-nitroacetophenone.
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IUPAC name of quinol is:

The total energy of the electron in a hydrogen atom is \( -1.51 \text{ eV} \).
A. Its Kinetic energy is \( -1.51 \text{ eV} \)
B. Its potential energy is \( -3.02 \text{ eV} \)
C. electron is in second excited state
D. The ground state energy of hydrogen atom is 13.6 eV
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The wavelength of light from the spectral emission line of sodium is 662 nm.
The kinetic energy at which an electron would have the same de-Broglie wavelength would be:
(Given: \( h = 6.62 \times 10^{-34} \text{ J s}, m_e = 9 \times 10^{-31} \text{ kg} \))

Answer the question on the basis of passage given below:
In the periodic table, the d-block contains the elements of group \(3\) to \(12\). The d-orbitals are progressively filled in each of the four long periods. The elements of d block referred as transition metals have partly filled d orbitals and exhibit certain characteristic properties such as variety of oxidation states, formation of coloured ions, act as catalyst and show paramagnetic behaviour.
The two inner transition metals series \(4f\) and \(5f\) are known as Lanthanoids and Actinoids respectively. The lanthanoids resemble one another more closely as compared to ordinary transition elements in any series.
For the four successive transition elements given below, the stability of +2 oxidation state will be:
A. \(\operatorname{Cr}( Z =24)\)
B. \(Mn ( Z =25)\)
C. \(Fe ( Z =26)\)
D. \(Co ( Z =27)\)
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The number of moles of electrons produced in the oxidation of 67.2 L of H 2 at STP is:

Five species of warblers studied by Mac Arthur is an example of :

Which of the following statements is correct for enantiomers?
(A) They exist as a pair of non-superimposable mirror images.
(B) They possess identical physical properties.
(C) They differ with respect to the rotation of plane polarized light.
(D) A mixture containing a 1:1 ratio of enantiomers is optically inactive.
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