CUET · CHEMISTRY · PYQ PAPER 2023
Chemically, which of the following hormones is a polypeptide?
- A Androgens
- B Endorphin
- C Epinephrine
- D Norepinephrine
Answer & Solution
Correct Answer
(B) Endorphin
Step-by-step Solution
Detailed explanation
Endorphin
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\(KMnO _4\) is prepared by the fusion of \(MnO _2\) with an alkali metal hydroxide and an oxidizing agent like \(KNO _3\) to give a dark-green manganate ion which disproportionate to give permanganate as follows.
\(\begin{array}{l}2 MnO _2+4 KOH + O _2 \rightarrow 2 K_2 MnO _4+2 H _2 O \\ 3 K_2 MnO _4+4 H ^{+} \rightarrow 2 KMnO _4+ MnO _2+2 H _2 O \end{array}\)
On heating \(K _2 MnO _4\) decomposes at 513 K to give \(K _2 MnO _4\). Permanganate ion is tetrahedral and diamagnetic
Acidified \(KMnO _4\) acts a strong oxidizing agent which oxidizes oxalic acid, ferrous ions, nitrite ion and iodides.
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Ethers with the general formula \(C _n H _{2 n+2} O\) and functional group C-O-C may be divided as symmetrical and unsymmetrical.
Lower symmetrical ether may be obtained by the dehydration of alcohols at low temperatures in the presence of protic acids,
such as \(H _2 SO _4\) and \(H _3 PO _4\) whereas at high temperature intramolecular dehydration takes place.
Formation of ether from primary alcohols is also accompanied by the formation of small amount of alkenes.
Due to the steric hinderance, secondary and tertiary alcohols undergo elimination reaction rather than substitution reaction yielding alkene as major product. Ethers can also be obtained by heating alkyl halides with sodium or potassium alkoxides.
Substituted Ethers (secondary & tertiary) can also be prepared using this method.
If primary halides are replaced with secondary and tertiary halides, alkenes are the major products.
The major product in the following reaction is
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